(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN

$772.53
Product name: (1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN
CAS: 105251-52-3
MF: C24H45N3O2Si2
MW: 463.8
EINECS:
MDL Number:MFCD00142698
Synonyms:(1S,9S)-1,9-BIS((T-BUTYLDIME.SILOXY)ME)- 5-CYANOSEMICORRIN;1,9-bis[(tert-butyldimethylsilyloxy)methyl]cyanosemicorrin;Semicorrin chiral ligand 2, (1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin;SEMICORRIN CHIRAL LIGAND 2;(1S,9S)-1,9-BIS[(TERT-BUTYLDIMETHYLSILOXY)METHYL]-5-CYANOSEMICORRIN;(1S, 9S)-(-)-1,9-BIS[(TERT-BUTYLDIMETHYLSILYLOXY)METHYL]-5-CYANOSEMICORRIN;(1S,9S)-1,9-Bis[(tert-butyldimethylsiloxy)methyl]-5-cyanosemicorrin >=97.0%;(1S,9S)-1,9-Bis{[(t-butyl)dimethylsilyloxy]methyl}-5-cyanosemicorrin

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ManufacturerAmerican Custom Chemicals Corporation
Product numberORS0000861
Product description(1S,9S)-1,9-BIS[(TERT-BUTYLDIMETHYLSILOXY)METHYL]-5-CYANOSEMICORRIN 95.00%
Packaging10MG
Price$772.53
Updated2021-12-16
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Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
American Custom Chemicals Corporation	ORS0000861	(1S,9S)-1,9-BIS[(TERT-BUTYLDIMETHYLSILOXY)METHYL]-5-CYANOSEMICORRIN 95.00%	10MG	$772.53	2021-12-16	Buy

Properties

Melting point :74-77 °C
storage temp. :2-8°C
optical activity :[α]20/D 63±2°, c = 1% in chloroform
BRN :5153664

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H315	Causes skin irritation	Skin corrosion/irritation	Category 2	Warning	P264, P280, P302+P352, P321,P332+P313, P362
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning

Precautionary statements:

P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

The Cu(II) and Co(II) complexes are catalysts for enantioselective cyclopropanation as well as reduction reactions.

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