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ChemicalBook >> CAS DataBase List >> 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate

1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate

1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate price.
  • $14 - $677
  • Product name: 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
  • CAS: 119752-83-9
  • MF: C6H12N2O4S2
  • MW: 240.29
  • EINECS:
  • MDL Number:MFCD22377802
  • Synonyms:1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate;1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct >=95% (sulfur, eleMental analysis);1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulfinate;Bis(sulfur Dioxide)-1,4-diazabicyclo[2.2.2]octane Adduct;1,4-diazabicyclo [2.2.2] octane-1,4-dinium-1,4-disulfonic acid;4-disulfinate;4-diium-1;4-Diazabicyclo[2.2.2]octane-1
22 prices
Selected condition:
Brand
  • AK Scientific
  • Ambeed
  • Apolloscientific
  • Biosynth Carbosynth
  • Chemenu
  • Matrix Scientific
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
Package
  • 50mg
  • 500mg
  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • 1000g
  • ManufacturerAK Scientific
  • Product number0758AD
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
  • Packaging5g
  • Price$333
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA415779
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 95%
  • Packaging1g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA415779
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 95%
  • Packaging5g
  • Price$52
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA415779
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 95%
  • Packaging25g
  • Price$186
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR310371
  • Product description1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate
  • Packaging1g
  • Price$44
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR310371
  • Product description1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate
  • Packaging5g
  • Price$167
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD111193
  • Product description1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
  • Packaging500mg
  • Price$65
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD111193
  • Product description1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
  • Packaging1g
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD111193
  • Product description1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
  • Packaging2g
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD111193
  • Product description1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
  • Packaging5G
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD111193
  • Product description1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
  • Packaging10g
  • Price$550
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM326152
  • Product description1,4-diazoniabicyclo[2.2.2]octane-1,4-disulfinate 95%+
  • Packaging1000g
  • Price$677
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number102536
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate >97%
  • Packaging500mg
  • Price$49
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number102536
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate >97%
  • Packaging1g
  • Price$66
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number102536
  • Product description1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate >97%
  • Packaging5g
  • Price$258
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number742937
  • Product description1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct ≥95% (sulfur, elemental analysis)
  • Packaging1g
  • Price$71.4
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 0758AD 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 5g $333 2021-12-16 Buy
Ambeed A415779 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 95% 1g $14 2021-12-16 Buy
Ambeed A415779 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 95% 5g $52 2021-12-16 Buy
Ambeed A415779 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 95% 25g $186 2021-12-16 Buy
Apolloscientific OR310371 1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate 1g $44 2021-12-16 Buy
Apolloscientific OR310371 1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate 5g $167 2021-12-16 Buy
Biosynth Carbosynth FD111193 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct 500mg $65 2021-12-16 Buy
Biosynth Carbosynth FD111193 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct 1g $100 2021-12-16 Buy
Biosynth Carbosynth FD111193 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct 2g $200 2021-12-16 Buy
Biosynth Carbosynth FD111193 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct 5G $320 2021-12-16 Buy
Biosynth Carbosynth FD111193 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct 10g $550 2021-12-16 Buy
Chemenu CM326152 1,4-diazoniabicyclo[2.2.2]octane-1,4-disulfinate 95%+ 1000g $677 2021-12-16 Buy
Matrix Scientific 102536 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate >97% 500mg $49 2021-12-16 Buy
Matrix Scientific 102536 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate >97% 1g $66 2021-12-16 Buy
Matrix Scientific 102536 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate >97% 5g $258 2021-12-16 Buy
Sigma-Aldrich 742937 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct ≥95% (sulfur, elemental analysis) 1g $71.4 2024-03-01 Buy

Properties

Melting point :180 °C(dec.)
storage temp. :2-8°C
Water Solubility :Soluble in water
form :powder to crystal
color :White to Almost white
InChIKey :RWISEVUOFYXWFO-UHFFFAOYSA-N
CAS DataBase Reference :119752-83-9

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) is a charge transfer complex that can be used as a sulfur dioxide surrogate:
  • In palladium-catalyzed aminosulfonylation process.
  • In reaction with aryl bromides to synthesize sodium aryl sulfinates.

It can also be used to activate DMSO and o-vinylanilines for the synthesis of N-aryl-1H-benzo[d]imidazol-1-amine and 4-aryl quinolines, respectively.

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