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ChemicalBook >> CAS DataBase List >> (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE price.
  • $189 - $3495
  • Product name: (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
  • CAS: 149341-33-3
  • MF: C31H22NP
  • MW: 439.49
  • EINECS:
  • MDL Number:MFCD01073773
  • Synonyms:(S)-QUINAP;(R)-QUINAP;R-QUINAR;(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline S-QUINAP;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline,98%;(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE;(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline >=95.0% (qNMR)
Price9 Properties Safety Information Description
9 prices
Selected condition：
Brand
  • Alichem
  • American Custom Chemicals Corporation
  • Arctom
  • BLDpharm
  • Sigma-Aldrich
Package
  • 50mg
  • 100MG
  • 250mg
  • 1g
  • 5g
  • ManufacturerAlichem
  • Product number149341333
  • Product description(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline
  • Packaging1g
  • Price$2439.6
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001331
  • Product description(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE 95.00%
  • Packaging100MG
  • Price$395.81
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS574257
  • Product description(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline ≥98%
  • Packaging1g
  • Price$3495
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD433914
  • Product description(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+%
  • Packaging100mg
  • Price$189
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD433914
  • Product description(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+%
  • Packaging250mg
  • Price$284
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD433914
  • Product description(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+%
  • Packaging1g
  • Price$715
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD433914
  • Product description(S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+%
  • Packaging5g
  • Price$2489
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number743585
  • Product description(S)-(?)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline ≥95.0% (qNMR)
  • Packaging50mg
  • Price$190
  • Updated2023-01-07
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number743585
  • Product description(S)-(?)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline ≥95.0% (qNMR)
  • Packaging250mg
  • Price$900
  • Updated2023-01-07
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alichem 149341333 (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 1g $2439.6 2021-12-16 Buy
American Custom Chemicals Corporation ING0001331 (S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE 95.00% 100MG $395.81 2021-12-16 Buy
Arctom AS574257 (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline ≥98% 1g $3495 2021-12-16 Buy
BLDpharm BD433914 (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+% 100mg $189 2021-12-16 Buy
BLDpharm BD433914 (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+% 250mg $284 2021-12-16 Buy
BLDpharm BD433914 (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+% 1g $715 2021-12-16 Buy
BLDpharm BD433914 (S)-1-(2-(Diphenylphosphino)naphthalen-1-yl)isoquinoline 98+% 5g $2489 2021-12-16 Buy
Sigma-Aldrich 743585 (S)-(?)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline ≥95.0% (qNMR) 50mg $190 2023-01-07 Buy
Sigma-Aldrich 743585 (S)-(?)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline ≥95.0% (qNMR) 250mg $900 2023-01-07 Buy

Properties

Melting point :220-230 °C
Boiling point :588.1±38.0 °C(Predicted)
storage temp. :2-8°C
pka :4.45±0.30(Predicted)
form :Crystalline Powder
color :White to off-white
BRN :6664856

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(S)-QUINAP can be used as a ligand:
  • In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)2.??????
  • For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.

[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.

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Aladdin Scientific J & K SCIENTIFIC LTD. Meryer (Shanghai) Chemical Technology Co., Ltd. Thermo Fisher Scientific Sigma-Aldrich Shanghai Chiral bio-compound co., Ltd. Shanghai Anyinuo Biomedical Technology Co., Ltd. Jiangsu aikang biomedical research and development co., LTD