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ChemicalBook >> CAS DataBase List >> (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

$28 - $4379
Product name: (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
CAS: 158923-09-2
MF: C36H44FeP210*
MW: 594.53
EINECS:
MDL Number:MFCD00800280
Synonyms:(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%;(r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas);(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS);(R)1[(1S)2(di-C-hex;(S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino

Price26 Properties Safety Information Description

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Brand

Aaron Chemicals
Ambeed
American Custom Chemicals Corporation
Arctom
ChemScene
Sigma-Aldrich
Strem Chemicals

Package

50mg
100mg
250mg
500MG
1g
2G
10g

ManufacturerAaron Chemicals
Product numberAR001RPF
Product descriptionFerrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%
Packaging1g
Price$177
Updated2021-12-16
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ManufacturerAaron Chemicals
Product numberAR001RPF
Product descriptionFerrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%
Packaging250mg
Price$70
Updated2021-12-16
Buy

ManufacturerAaron Chemicals
Product numberAR001RPF
Product descriptionFerrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%
Packaging100mg
Price$38
Updated2021-12-16
Buy

ManufacturerAaron Chemicals
Product numberAR001RPF
Product descriptionFerrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%
Packaging50mg
Price$28
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA405325
Product description(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging50mg
Price$28
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA405325
Product description(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging100mg
Price$38
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA405325
Product description(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging250mg
Price$68
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA405325
Product description(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging1g
Price$218
Updated2021-12-16
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ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001267
Product description(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%
Packaging100MG
Price$646.88
Updated2021-12-16
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ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001267
Product description(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%
Packaging500MG
Price$914.17
Updated2021-12-16
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ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001267
Product description(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%
Packaging1G
Price$1269.75
Updated2021-12-16
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ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001267
Product description(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%
Packaging2G
Price$1765
Updated2021-12-16
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ManufacturerArctom
Product numberAS548072
Product description(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging50mg
Price$28
Updated2021-12-16
Buy

ManufacturerArctom
Product numberAS548072
Product description(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging100mg
Price$38
Updated2021-12-16
Buy

ManufacturerArctom
Product numberAS548072
Product description(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging250mg
Price$67
Updated2021-12-16
Buy

ManufacturerArctom
Product numberAS548072
Product description(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%
Packaging1g
Price$216
Updated2021-12-16
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Aaron Chemicals	AR001RPF	Ferrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%	1g	$177	2021-12-16	Buy
Aaron Chemicals	AR001RPF	Ferrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%	250mg	$70	2021-12-16	Buy
Aaron Chemicals	AR001RPF	Ferrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%	100mg	$38	2021-12-16	Buy
Aaron Chemicals	AR001RPF	Ferrocene,1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-,(1R)- 95%	50mg	$28	2021-12-16	Buy
Ambeed	A405325	(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	50mg	$28	2021-12-16	Buy
Ambeed	A405325	(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	100mg	$38	2021-12-16	Buy
Ambeed	A405325	(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	250mg	$68	2021-12-16	Buy
Ambeed	A405325	(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	1g	$218	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001267	(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%	100MG	$646.88	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001267	(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%	500MG	$914.17	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001267	(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%	1G	$1269.75	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001267	(R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYLETHYL]DIPHENYLPHOSPHINE 95.00%	2G	$1765	2021-12-16	Buy
Arctom	AS548072	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	50mg	$28	2021-12-16	Buy
Arctom	AS548072	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	100mg	$38	2021-12-16	Buy
Arctom	AS548072	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	250mg	$67	2021-12-16	Buy
Arctom	AS548072	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine 98%	1g	$216	2021-12-16	Buy

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Properties

alpha :-100° ±5° (c 0.5, CHCl3)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :orange

Safety Information

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H302	Harmful if swallowed	Acute toxicity,oral	Category 4	Warning	P264, P270, P301+P312, P330, P501
H315	Causes skin irritation	Skin corrosion/irritation	Category 2	Warning	P264, P280, P302+P352, P321,P332+P313, P362
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning

Precautionary statements:

P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352	IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

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