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ChemicalBook >> CAS DataBase List >> (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% price.
  • $96 - $4824
  • Product name: (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • CAS: 167709-31-1
  • MF: C70H96O2P2
  • MW: 1031.46
  • EINECS:
  • MDL Number:MFCD09753001
  • Synonyms:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(S)-3,5-t-Bu-MeOBIPHEP, SL-A121-2, (S)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl;(S)-(-)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(S)-3,5-t-Bu-MeOBIPHEP;SL-A121-2;(S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl
14 prices
Selected condition:
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • BLDpharm
  • Strem Chemicals
Package
  • 100mg
  • 250mg
  • 500MG
  • 1g
  • 2G
  • 10g
  • ManufacturerAmbeed
  • Product numberA685121
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging100mg
  • Price$106
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685121
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging250mg
  • Price$233
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685121
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging1g
  • Price$665
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001344
  • Product description(S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging100MG
  • Price$647.13
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001344
  • Product description(S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging500MG
  • Price$914.41
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001344
  • Product description(S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging1G
  • Price$1269.75
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001344
  • Product description(S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging2G
  • Price$1765
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633930
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging100mg
  • Price$107
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633930
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging250mg
  • Price$235
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633930
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging1g
  • Price$696
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0045
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
  • Packaging100mg
  • Price$96
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0045
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
  • Packaging500mg
  • Price$355
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0045
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
  • Packaging2g
  • Price$1207
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0045
  • Product description(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
  • Packaging10g
  • Price$4824
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A685121 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 100mg $106 2021-12-16 Buy
Ambeed A685121 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 250mg $233 2021-12-16 Buy
Ambeed A685121 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 1g $665 2021-12-16 Buy
American Custom Chemicals Corporation ING0001344 (S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 100MG $647.13 2021-12-16 Buy
American Custom Chemicals Corporation ING0001344 (S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 500MG $914.41 2021-12-16 Buy
American Custom Chemicals Corporation ING0001344 (S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 1G $1269.75 2021-12-16 Buy
American Custom Chemicals Corporation ING0001344 (S)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 2G $1765 2021-12-16 Buy
BLDpharm BD633930 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 100mg $107 2021-12-16 Buy
BLDpharm BD633930 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 250mg $235 2021-12-16 Buy
BLDpharm BD633930 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 1g $696 2021-12-16 Buy
Strem Chemicals 15-0045 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 100mg $96 2024-03-01 Buy
Strem Chemicals 15-0045 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 500mg $355 2024-03-01 Buy
Strem Chemicals 15-0045 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 2g $1207 2024-03-01 Buy
Strem Chemicals 15-0045 (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 10g $4824 2024-03-01 Buy

Properties

Boiling point :856.5±65.0 °C(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :white

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(S)-3,5-t-Bu-MeOBIPHEP can be used as a ligand in the stereoselective preparation of allenoates via palladium-catalyzed asymmetric carbonylation of propargylic carbonates. It can also be used in the C-C coupling reactions.

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