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ChemicalBook >> CAS DataBase List >> (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE

(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE

(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE price.
  • $153 - $862
  • Product name: (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE
  • CAS: 180675-22-3
  • MF: C4H7BrMgO2
  • MW: 191.31
  • EINECS:
  • MDL Number:MFCD01321271
  • Synonyms:(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE;(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMI DE, 1.0M SOLUTION IN THF;(1,3-dioxolan-2-ylmethyl)magnesium bromide solution;(1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide, 0.5M solution in THF, AcroSeal;Bromo(1,3-dioxolan-2-ylmethyl)magnesium;MagnesiuM,broMo(1,3-dioxolan-2-ylMethyl)-;(1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide solution 0.5 M in THF;1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in THF
Price13 Properties Safety Information Description
13 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • Matrix Scientific
  • Rieke Metals
  • Sigma-Aldrich
Package
  • 5MG
  • 50ml
  • 100ml
  • 500ml
  • 1l
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0015639
  • Product description(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE 95.00%
  • Packaging5MG
  • Price$505.87
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121789
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50MinTHF97%
  • Packaging50ml
  • Price$232
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121788
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50Min2-MeTHF97%
  • Packaging50ml
  • Price$232
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121789
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50MinTHF97%
  • Packaging100ml
  • Price$332
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121788
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50Min2-MeTHF97%
  • Packaging100ml
  • Price$332
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121788
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50Min2-MeTHF97%
  • Packaging500ml
  • Price$737
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121789
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50MinTHF97%
  • Packaging500ml
  • Price$737
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberT0225
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide
  • Packaging50mL
  • Price$153
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberG0225
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide
  • Packaging50mL
  • Price$153
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberT0225
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide
  • Packaging100mL
  • Price$293
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product numberG0225
  • Product description1,3-Dioxolan-2-ylmethylmagnesiumbromide
  • Packaging100mL
  • Price$293
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number472611
  • Product description(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 0.5 M in THF
  • Packaging100ml
  • Price$184
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number472611
  • Product description(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 0.5 M in THF
  • Packaging1l
  • Price$862
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation ING0015639 (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE 95.00% 5MG $505.87 2021-12-16 Buy
Matrix Scientific 121789 1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50MinTHF97% 50ml $232 2021-12-16 Buy
Matrix Scientific 121788 1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50Min2-MeTHF97% 50ml $232 2021-12-16 Buy
Matrix Scientific 121789 1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50MinTHF97% 100ml $332 2021-12-16 Buy
Matrix Scientific 121788 1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50Min2-MeTHF97% 100ml $332 2021-12-16 Buy
Matrix Scientific 121788 1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50Min2-MeTHF97% 500ml $737 2021-12-16 Buy
Matrix Scientific 121789 1,3-Dioxolan-2-ylmethylmagnesiumbromide 0.50MinTHF97% 500ml $737 2021-12-16 Buy
Rieke Metals T0225 1,3-Dioxolan-2-ylmethylmagnesiumbromide 50mL $153 2021-12-16 Buy
Rieke Metals G0225 1,3-Dioxolan-2-ylmethylmagnesiumbromide 50mL $153 2021-12-16 Buy
Rieke Metals T0225 1,3-Dioxolan-2-ylmethylmagnesiumbromide 100mL $293 2021-12-16 Buy
Rieke Metals G0225 1,3-Dioxolan-2-ylmethylmagnesiumbromide 100mL $293 2021-12-16 Buy
Sigma-Aldrich 472611 (1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 0.5 M in THF 100ml $184 2024-03-01 Buy
Sigma-Aldrich 472611 (1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 0.5 M in THF 1l $862 2024-03-01 Buy

Properties

Boiling point :65-67 °C
Density :0.938 g/mL at 25 °C
Flash point :−4 °F
form :Powder
color :White to off-white to pale brown

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

(1,3-Dioxolan-2-ylmethyl)magnesium bromide is a Grignard reagent that can be used to prepare:
  • 3-[11C]-Propionaldehyde, a key intermediate for the synthesis of radiolabeled compound [11C]SN-38, wherein SN-38 is 7-ethyl-10-hydroxy camptothecin.
  • 1-[(S)-2,2-Dimethyl-(1,3)-dioxolan-4-yl]-4-(1,3-dioxolan2-yl)-2-ol by reacting with D-glyceraldehyde, which is further used to synthesize unsaturated nucleosides.
  • A bicyclo carboxylate intermediate, which is employed in the total synthesis of spirovibsanin A.

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