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ChemicalBook >> CAS DataBase List >> 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE price.
  • $95 - $1350
  • Product name: 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
  • CAS: 18388-03-9
  • MF: C7H15ClSi
  • MW: 162.73
  • EINECS:
  • MDL Number:MFCD00013253
  • Synonyms:2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE;2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE;[2-(Chloromethyl)-2-propenyl]trimethylsilane;2-(Trimethylsilylmethyl)-2-propenyl chloride;2-(Trimethylsilylmethyl)-3-chloro-1-propene;2-Methylene-3-chloropropyltrimethylsilane;2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
5 prices
Selected condition:
Brand
  • AHH
  • Arctom
  • Sigma-Aldrich
  • TRC
Package
  • 500mg
  • 1g
  • 5g
  • 10g
  • ManufacturerAHH
  • Product numberMT-05953
  • Product description2-Chloromethyl-3-trimethylsilyl-1-propene 97%
  • Packaging10g
  • Price$318
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY248950
  • Product description[2-(Chloromethyl)allyl]trimethylsilane ≥97%
  • Packaging1g
  • Price$1350
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number318345
  • Product description2-(Chloromethyl)allyl-trimethylsilane 97%
  • Packaging1g
  • Price$116
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number318345
  • Product description2-(Chloromethyl)allyl-trimethylsilane 97%
  • Packaging5g
  • Price$414
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberC371430
  • Product description2-​(Chloromethyl)​allyl-​trimethylsilane
  • Packaging500mg
  • Price$95
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-05953 2-Chloromethyl-3-trimethylsilyl-1-propene 97% 10g $318 2021-12-16 Buy
Arctom SY248950 [2-(Chloromethyl)allyl]trimethylsilane ≥97% 1g $1350 2021-12-16 Buy
Sigma-Aldrich 318345 2-(Chloromethyl)allyl-trimethylsilane 97% 1g $116 2024-03-01 Buy
Sigma-Aldrich 318345 2-(Chloromethyl)allyl-trimethylsilane 97% 5g $414 2024-03-01 Buy
TRC C371430 2-​(Chloromethyl)​allyl-​trimethylsilane 500mg $95 2021-12-16 Buy

Properties

Boiling point :162-163 °C/768 mmHg (lit.)
Density :0.899 g/mL at 25 °C (lit.)
refractive index :n20/D 1.453(lit.)
Flash point :110 °F
storage temp. :2-8°C
solubility :Chloroform, Methanol (Slightly)
form :Oil
color :Clear Colourless
Specific Gravity :0.899
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
BRN :1747038
Stability :Moisture Sensitive

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones.

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