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ChemicalBook >> CAS DataBase List >> (S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI-TERT.-BUTYLPHOSPHINE

(S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI-TERT.-BUTYLPHOSPHINE

(S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI-TERT.-BUTYLPHOSPHINE price.
  • $48 - $3863
  • Product name: (S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI-TERT.-BUTYLPHOSPHINE
  • CAS: 277306-29-3
  • MF: C32H40FeP2
  • MW: 542.45
  • EINECS:
  • MDL Number:MFCD01074443
  • Synonyms:(S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI-TERT.-BUTYLPHOSPHINE;(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%;(s,s)-1-[1-(di-tert-butylphosphino)ethyl]-2-(diphenylphosphino]ferrocene (acc to cas);(S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE, MIN. 97%;(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;Josiphos SL-J002-2, (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS);(2R)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene;(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
20 prices
Selected condition:
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • Arctom
  • ChemScene
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 100MG
  • 250mg
  • 500mg
  • 1G
  • 2g
  • 10g
  • ManufacturerAK Scientific
  • Product number7511AJ
  • Product description(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • Packaging500mg
  • Price$316
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001366
  • Product description(S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 95.00%
  • Packaging100MG
  • Price$646.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001366
  • Product description(S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 95.00%
  • Packaging500MG
  • Price$914.17
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001366
  • Product description(S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 95.00%
  • Packaging1G
  • Price$1269.75
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS609327
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 98%
  • Packaging100mg
  • Price$48
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS609327
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 98%
  • Packaging250mg
  • Price$87
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS609327
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 98%
  • Packaging1g
  • Price$265
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY074653
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene ≥97%
  • Packaging1g
  • Price$695
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0031529
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene ≥97.0%
  • Packaging250mg
  • Price$88
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0031529
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene ≥97.0%
  • Packaging1g
  • Price$268
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51001326
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 97%
  • Packaging100mg
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51001326
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 97%
  • Packaging250mg
  • Price$192
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51001326
  • Product description(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 97%
  • Packaging1g
  • Price$580
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number88720
  • Product description(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97%
  • Packaging100mg
  • Price$103
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number88720
  • Product description(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97%
  • Packaging1g
  • Price$204.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number88720
  • Product description(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97%
  • Packaging500mg
  • Price$359
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 7511AJ (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 500mg $316 2021-12-16 Buy
American Custom Chemicals Corporation ING0001366 (S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 95.00% 100MG $646.88 2021-12-16 Buy
American Custom Chemicals Corporation ING0001366 (S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 95.00% 500MG $914.17 2021-12-16 Buy
American Custom Chemicals Corporation ING0001366 (S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE 95.00% 1G $1269.75 2021-12-16 Buy
Arctom AS609327 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 98% 100mg $48 2021-12-16 Buy
Arctom AS609327 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 98% 250mg $87 2021-12-16 Buy
Arctom AS609327 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 98% 1g $265 2021-12-16 Buy
Arctom SY074653 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene ≥97% 1g $695 2021-12-16 Buy
ChemScene CS-0031529 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene ≥97.0% 250mg $88 2021-12-16 Buy
ChemScene CS-0031529 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene ≥97.0% 1g $268 2021-12-16 Buy
Crysdot CD51001326 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 97% 100mg $90 2021-12-16 Buy
Crysdot CD51001326 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 97% 250mg $192 2021-12-16 Buy
Crysdot CD51001326 (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene 97% 1g $580 2021-12-16 Buy
Sigma-Aldrich 88720 (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97% 100mg $103 2024-03-01 Buy
Sigma-Aldrich 88720 (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97% 1g $204.8 2024-03-01 Buy
Sigma-Aldrich 88720 (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97% 500mg $359 2024-03-01 Buy

Properties

alpha :+412° ±15° (c 0.5, CHCl3)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :orange
optical activity :[α]20/D +410±15°, c = 0.5 in chloroform

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine is β-boration catalyst; used in preparation of Sitagliptin β-Amino-2,4,5-trifluorobenzenebutanoic Acid derivatives intermediates via Grignard exchange reaction, cross coupling, β-boration, oxidation and Amination.