(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
- $67 - $547
- Product name: (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
- CAS: 364732-88-7
- MF: C40H34P2
- MW: 576.65
- EINECS:
- MDL Number:MFCD03094575
- Synonyms:(R)-Phanephos, 98%, ee 98%;(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%;(Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane;Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee
14 prices
Selected condition:
Brand
- Alfa Aesar
- Ambeed
- Arctom
- BLDpharm
- Sigma-Aldrich
- Strem Chemicals
Package
- 50mg
- 100mg
- 250mg
- 500mg
- ManufacturerAlfa Aesar
- Product numberH25812
- Product description(R)-Phanephos, 98%, ee 98%
- Packaging250mg
- Price$139.18
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA174075
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging50mg
- Price$75
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA174075
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging100mg
- Price$132
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA174075
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging250mg
- Price$285
- Updated2021-12-16
- Buy
- ManufacturerArctom
- Product numberAS463635
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging50mg
- Price$67
- Updated2021-12-16
- Buy
- ManufacturerArctom
- Product numberAS463635
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging100mg
- Price$117
- Updated2021-12-16
- Buy
- ManufacturerArctom
- Product numberAS463635
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging250mg
- Price$256
- Updated2021-12-16
- Buy
- ManufacturerBLDpharm
- Product numberBD634145
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging50mg
- Price$68
- Updated2021-12-16
- Buy
- ManufacturerBLDpharm
- Product numberBD634145
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging100mg
- Price$118
- Updated2021-12-16
- Buy
- ManufacturerBLDpharm
- Product numberBD634145
- Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
- Packaging250mg
- Price$259
- Updated2021-12-16
- Buy
- ManufacturerSigma-Aldrich
- Product number682144
- Product description(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96%
- Packaging100mg
- Price$120
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number682144
- Product description(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96%
- Packaging500mg
- Price$547
- Updated2024-03-01
- Buy
- ManufacturerStrem Chemicals
- Product number15-0425
- Product description(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
- Packaging100mg
- Price$102
- Updated2024-03-01
- Buy
- ManufacturerStrem Chemicals
- Product number15-0425
- Product description(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
- Packaging500mg
- Price$412
- Updated2024-03-01
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
Alfa Aesar | H25812 | (R)-Phanephos, 98%, ee 98% | 250mg | $139.18 | 2021-12-16 | Buy |
Ambeed | A174075 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 50mg | $75 | 2021-12-16 | Buy |
Ambeed | A174075 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 100mg | $132 | 2021-12-16 | Buy |
Ambeed | A174075 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 250mg | $285 | 2021-12-16 | Buy |
Arctom | AS463635 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 50mg | $67 | 2021-12-16 | Buy |
Arctom | AS463635 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 100mg | $117 | 2021-12-16 | Buy |
Arctom | AS463635 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 250mg | $256 | 2021-12-16 | Buy |
BLDpharm | BD634145 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 50mg | $68 | 2021-12-16 | Buy |
BLDpharm | BD634145 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 100mg | $118 | 2021-12-16 | Buy |
BLDpharm | BD634145 | (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% | 250mg | $259 | 2021-12-16 | Buy |
Sigma-Aldrich | 682144 | (R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96% | 100mg | $120 | 2024-03-01 | Buy |
Sigma-Aldrich | 682144 | (R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96% | 500mg | $547 | 2024-03-01 | Buy |
Strem Chemicals | 15-0425 | (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS | 100mg | $102 | 2024-03-01 | Buy |
Strem Chemicals | 15-0425 | (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS | 500mg | $412 | 2024-03-01 | Buy |
Properties
Melting point :222-225°C
alpha :-62.6° (c 3.11, CH2Cl2)
storage temp. :Inert atmosphere,Room Temperature
form :solid
color :white
optical activity :[α]/D -34±4°, c = 1 in chloroform
CAS DataBase Reference :364732-88-7
alpha :-62.6° (c 3.11, CH2Cl2)
storage temp. :Inert atmosphere,Room Temperature
form :solid
color :white
optical activity :[α]/D -34±4°, c = 1 in chloroform
CAS DataBase Reference :364732-88-7
Safety Information
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Description
(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane may be used as a ligand in the following processes:Enantioselective reductive cyclization of 1,6-enynes via asymmetric hydrogenation in the presence of a rhodium catalyst to form alkylidene-substituted heterocycles.Asymmetric hydroboration of 3,3-disubstituted cyclopropenes to form 2,2-disubstituted cyclopropyl boronates.Asymmetric ring-opening reactions of azabenzonorbornadienes in the presence of zinc(II) triflate and palladium(II) acetate to form aminodihydronaphthalenes.More related product prices
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