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ChemicalBook >> CAS DataBase List >> (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P

(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P

(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P price.
  • $92.8 - $19850
  • Product name: (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
  • CAS: 387868-06-6
  • MF: C46H32F12FeP210*
  • MW: 930.52
  • EINECS:
  • MDL Number:MFCD04112740
  • Synonyms:(R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluor;(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine,min.97%;(r)-1-{(r)-2-[2-(diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine;(r,r)-1-{1-[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl}-2-[2-(diphenylphosphino)phenyl]ferrocene (acc to cas);(R)-(-)-1-[(R)-2-(2'DIPHENYLPHOSPHINOPHENYL)FERROCANYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE;(R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLBIS[3,5-BIS-(TRIFLUOROMETHYL)PHENYL]PHOSPHINE;(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P;(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE
Price9 Properties Safety Information Description
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Brand
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
Package
  • 100MG
  • 500MG
  • 1G
  • 5g
  • 50g
  • 100g
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001263
  • Product description(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLBIS(DI-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE 95.00%
  • Packaging100MG
  • Price$646.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001263
  • Product description(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLBIS(DI-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE 95.00%
  • Packaging500MG
  • Price$914.17
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001263
  • Product description(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLBIS(DI-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE 95.00%
  • Packaging1G
  • Price$1269.75
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging100g
  • Price$19850
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging50g
  • Price$19800
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging5g
  • Price$2760
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging1g
  • Price$684
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging500mg
  • Price$393
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging100mg
  • Price$92.8
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation ING0001263 (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLBIS(DI-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE 95.00% 100MG $646.88 2021-12-16 Buy
American Custom Chemicals Corporation ING0001263 (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLBIS(DI-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE 95.00% 500MG $914.17 2021-12-16 Buy
American Custom Chemicals Corporation ING0001263 (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLBIS(DI-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE 95.00% 1G $1269.75 2021-12-16 Buy
Sigma-Aldrich 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 100g $19850 2024-03-01 Buy
Sigma-Aldrich 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 50g $19800 2024-03-01 Buy
Sigma-Aldrich 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 5g $2760 2024-03-01 Buy
Sigma-Aldrich 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 1g $684 2023-06-20 Buy
Sigma-Aldrich 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 500mg $393 2024-03-01 Buy
Sigma-Aldrich 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 100mg $92.8 2024-03-01 Buy

Properties

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Description

Walphos SL-W001-1, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:
  • Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
  • Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2

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