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18162-48-6872-50-4Methylene ChloridenaphthaleneTHFTitanium Dioxide
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ChemicalBook >> CAS DataBase List >> (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT price.
  • $58 - $1928.85
  • Product name: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
  • CAS: 415918-91-1
  • MF: C36H30NO2P
  • MW: 539.61
  • EINECS:
  • MDL Number:MFCD04117687
  • Synonyms:(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS);(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct;(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
Price12 Properties Safety Information Description
12 prices
Selected condition：
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 50mg
  • 100mg
  • 200mg
  • 250mg
  • 500MG
  • 1g
  • 2G
  • 5g
  • ManufacturerAmbeed
  • Product numberA385864
  • Product description(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
  • Packaging100mg
  • Price$58
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA385864
  • Product description(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
  • Packaging250mg
  • Price$108
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA385864
  • Product description(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
  • Packaging1g
  • Price$358
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA385864
  • Product description(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee
  • Packaging5g
  • Price$1255
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0009373
  • Product description(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT 95.00%
  • Packaging100MG
  • Price$631.85
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0009373
  • Product description(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT 95.00%
  • Packaging500MG
  • Price$932.61
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0009373
  • Product description(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT 95.00%
  • Packaging2G
  • Price$1928.85
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1520
  • Product description(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
  • Packaging100mg
  • Price$86
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1520
  • Product description(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
  • Packaging500mg
  • Price$335
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberD4994
  • Product description(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC)
  • Packaging200mg
  • Price$174
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberD4994
  • Product description(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC)
  • Packaging1g
  • Price$531
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberD455833
  • Product description(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine
  • Packaging50mg
  • Price$110
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A385864 (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee 100mg $58 2021-12-16 Buy
Ambeed A385864 (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee 250mg $108 2021-12-16 Buy
Ambeed A385864 (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee 1g $358 2021-12-16 Buy
Ambeed A385864 (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 98%99%ee 5g $1255 2021-12-16 Buy
American Custom Chemicals Corporation HCH0009373 (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT 95.00% 100MG $631.85 2021-12-16 Buy
American Custom Chemicals Corporation HCH0009373 (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT 95.00% 500MG $932.61 2021-12-16 Buy
American Custom Chemicals Corporation HCH0009373 (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE, DICHLOROMETHANE ADDUCT 95.00% 2G $1928.85 2021-12-16 Buy
Strem Chemicals 15-1520 (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% 100mg $86 2024-03-01 Buy
Strem Chemicals 15-1520 (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% 500mg $335 2024-03-01 Buy
TCI Chemical D4994 (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC) 200mg $174 2024-03-01 Buy
TCI Chemical D4994 (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC) 1g $531 2024-03-01 Buy
TRC D455833 (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine 50mg $110 2021-12-16 Buy

Properties

Melting point :102-103 °C
Boiling point :710.7±63.0 °C(Predicted)
alpha :+427° (c 0.83, CHCl3)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :-0.57±0.20(Predicted)
form :Powder
color :white
Sensitive :moisture sensitive
CAS DataBase Reference :415918-91-1

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Used in a palladium-catalyzed diethylzinc mediated umpolung allylation. Chiral phosphoramidite ligand used in a highly enantioselective copper-catalyzed conjugate addition of diakylzincs to a variety of Michael acceptors.

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