(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
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- $95 - $632
- Product name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
- CAS: 500997-69-3
- MF: C33H32NO2P
- MW: 505.59
- EINECS:
- MDL Number:MFCD08459342
- Synonyms:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE;(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1-PHENYLETHYL]AMINE;N-DI[(R)-1-PHENYLETHYL]-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;N-DI[(R)-1-PHENYLETHYL]-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine,min.98%(R)-SIPHOS-PE;N-Di[(R)-1-phenylethyl]-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite ,98%;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine;(11aR)-10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-aMine
6 prices
Selected condition:
Brand
- AK Scientific
- ChemScene
- Sigma-Aldrich
- Strem Chemicals
Package
- 50mg
- 100mg
- 500mg
- ManufacturerAK Scientific
- Product number2465AQ
- Product description(Ra,R,R)-SIPHOS-PE
- Packaging50mg
- Price$352.4
- Updated2021-12-16
- Buy
- ManufacturerChemScene
- Product numberCS-0037331
- Product description(R)-SIPHOS-PE ≥97.0%
- Packaging50mg
- Price$95
- Updated2021-12-16
- Buy
- ManufacturerChemScene
- Product numberCS-0037331
- Product description(R)-SIPHOS-PE ≥97.0%
- Packaging100mg
- Price$185
- Updated2021-12-16
- Buy
- ManufacturerSigma-Aldrich
- Product number700770
- Product description(R)-SIPHOS-PE 97%
- Packaging50mg
- Price$190
- Updated2022-05-15
- Buy
- ManufacturerStrem Chemicals
- Product number15-5162
- Product description(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE
- Packaging100mg
- Price$160
- Updated2024-03-01
- Buy
- ManufacturerStrem Chemicals
- Product number15-5162
- Product description(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE
- Packaging500mg
- Price$632
- Updated2024-03-01
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
AK Scientific | 2465AQ | (Ra,R,R)-SIPHOS-PE | 50mg | $352.4 | 2021-12-16 | Buy |
ChemScene | CS-0037331 | (R)-SIPHOS-PE ≥97.0% | 50mg | $95 | 2021-12-16 | Buy |
ChemScene | CS-0037331 | (R)-SIPHOS-PE ≥97.0% | 100mg | $185 | 2021-12-16 | Buy |
Sigma-Aldrich | 700770 | (R)-SIPHOS-PE 97% | 50mg | $190 | 2022-05-15 | Buy |
Strem Chemicals | 15-5162 | (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE | 100mg | $160 | 2024-03-01 | Buy |
Strem Chemicals | 15-5162 | (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE | 500mg | $632 | 2024-03-01 | Buy |
Properties
Melting point :98-100°C
alpha :+300° (c 1.0, CH2Cl2)
Boiling point :617.8±65.0 °C(Predicted)
storage temp. :-20°C
pka :0.40±0.20(Predicted)
form :solid
color :white
optical activity :[α]22/D +337°, c = 1 in chloroform
Sensitive :moisture sensitive
InChIKey :ZXLQLIDJAURBDD-HRPAVAKOSA-N
alpha :+300° (c 1.0, CH2Cl2)
Boiling point :617.8±65.0 °C(Predicted)
storage temp. :-20°C
pka :0.40±0.20(Predicted)
form :solid
color :white
optical activity :[α]22/D +337°, c = 1 in chloroform
Sensitive :moisture sensitive
InChIKey :ZXLQLIDJAURBDD-HRPAVAKOSA-N
Safety Information
Symbol(GHS): |
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Description
(R)-SIPHOS-PE can be used as:- A catalyst in the preparation of tricyclic alkaloid (+)-aphanorphine via asymmetric carboamination and Friedel?Crafts reaction.
- A ligand in the synthesis of chiral ketones via hydroacylation of olefins using salicylaldehyde derivatives.
- A ligand in the enantioselective synthesis of substituted pyrrolidine derivatives via Pd-catalyzed alkene aminoarylation reactions.
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