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ChemicalBook >> CAS DataBase List >> (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE price.
  • $155 - $850.14
  • Product name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
  • CAS: 500997-70-6
  • MF: C33H32NO2P
  • MW: 505.59
  • EINECS:
  • MDL Number:MFCD08459342
  • Synonyms:(R)-SIPHOS-PE;(S)-SIPHOS-PE;N-DI[(R)-1-PHENYLETHYL]-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;N-DI[(R)-1-PHENYLETHYL]-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1-PHENYLETHYL]AMINE;(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE;(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine,min.98%(S)-SIPHOS-PE;(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ, 7μ-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, N-Di[(R)-1-phenylethyl]-[(S)-1,1μ-spirobiindane-7,7μ-diyl]-phosphoramidite
Price6 Properties Safety Information Description
6 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 50MG
  • 100mg
  • 250MG
  • 500mg
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0001800
  • Product description(S)-SIPHOS-PE 95.00%
  • Packaging50MG
  • Price$621.89
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0001800
  • Product description(S)-SIPHOS-PE 95.00%
  • Packaging250MG
  • Price$850.14
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number700762
  • Product description(S)-SIPHOS-PE 97%
  • Packaging50mg
  • Price$155
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number700762
  • Product description(S)-SIPHOS-PE 97%
  • Packaging250mg
  • Price$244
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-5163
  • Product description(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE
  • Packaging100mg
  • Price$160
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-5163
  • Product description(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE
  • Packaging500mg
  • Price$632
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation CCH0001800 (S)-SIPHOS-PE 95.00% 50MG $621.89 2021-12-16 Buy
American Custom Chemicals Corporation CCH0001800 (S)-SIPHOS-PE 95.00% 250MG $850.14 2021-12-16 Buy
Sigma-Aldrich 700762 (S)-SIPHOS-PE 97% 50mg $155 2023-06-20 Buy
Sigma-Aldrich 700762 (S)-SIPHOS-PE 97% 250mg $244 2024-03-01 Buy
Strem Chemicals 15-5163 (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE 100mg $160 2024-03-01 Buy
Strem Chemicals 15-5163 (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE 500mg $632 2024-03-01 Buy

Properties

Melting point :99-101°C
alpha :-63.5° (c 1.0, CH2Cl2)
Boiling point :617.8±65.0 °C(Predicted)
storage temp. :-20°C
pka :0.40±0.20(Predicted)
form :solid
color :white
optical activity :[α]22/D 65.0°, c = 1 in chloroform
Sensitive :moisture sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:
  • Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
  • Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones.
  • Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.

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