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ChemicalBook >> CAS DataBase List >> Methyl formate

Methyl formate

Methyl formate price.
  • $17 - $2347.13
  • Product name: Methyl formate
  • CAS: 107-31-3
  • MF: C2H4O2
  • MW: 60.05
  • EINECS:203-481-7
  • MDL Number:MFCD00003291
  • Synonyms:acid-Me;Formiate de methyle;Methyl ester of formic acid;methyle(formiatede) ;methyle(formiatede)(french) ;Methylester kyseliny mravenci;methylesterkyselinymravenci ;Methylformiaat
23 prices
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Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • GFS CHEMICALS
  • Medical Isotopes, Inc.
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
  • 5ml
  • 25mL
  • 500ml
  • 2l
  • 2.5L
  • 4l
  • sample
  • 50g
  • 100ML
  • 100g
  • 1L
  • 2500ml
  • 10000ml
  • ManufacturerAlfa Aesar
  • Product numberA15850
  • Product descriptionMethyl formate, 97%, may cont. up to ca 3% methanol
  • Packaging500ml
  • Price$32.7
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA15850
  • Product descriptionMethyl formate, 97%, may cont. up to ca 3% methanol
  • Packaging2500ml
  • Price$68.9
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA15850
  • Product descriptionMethyl formate, 97%, may cont. up to ca 3% methanol
  • Packaging10000ml
  • Price$187.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0118139
  • Product descriptionCARBOXYLIC ACID METHYL ESTER 95.00%
  • Packaging100ML
  • Price$2347.13
  • Updated2021-12-16
  • Buy
  • ManufacturerGFS CHEMICALS
  • Product number16232
  • Product descriptionMETHYLFORMATE,97%
  • Packaging500mL
  • Price$94.32
  • Updated2021-12-16
  • Buy
  • ManufacturerMedical Isotopes, Inc.
  • Product number71434
  • Product descriptionMethyl Formate
  • Packaging100g
  • Price$775
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number8.00889
  • Product descriptionMethyl formate for synthesis
  • Packaging100mL
  • Price$32.6
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number8.00889
  • Product descriptionMethyl formate for synthesis
  • Packaging1L
  • Price$51.2
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product numberW519103
  • Product descriptionMethyl formate ≥95%
  • Packagingsample
  • Price$52
  • Updated2022-05-15
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number291056
  • Product descriptionMethyl formate anhydrous, 99%
  • Packaging100ml
  • Price$77.1
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number06547
  • Product descriptionMethyl formate analytical standard
  • Packaging5ml
  • Price$96.4
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number8.00889
  • Product descriptionMethyl formate for synthesis
  • Packaging2.5L
  • Price$100
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product numberM46837
  • Product descriptionMethyl formate reagent grade, 97%
  • Packaging1l
  • Price$111
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number291056
  • Product descriptionMethyl formate anhydrous, 99%
  • Packaging1l
  • Price$170
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product numberM46837
  • Product descriptionMethyl formate reagent grade, 97%
  • Packaging4l
  • Price$230
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number291056
  • Product descriptionMethyl formate anhydrous, 99%
  • Packaging2l
  • Price$257
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar A15850 Methyl formate, 97%, may cont. up to ca 3% methanol 500ml $32.7 2024-03-01 Buy
Alfa Aesar A15850 Methyl formate, 97%, may cont. up to ca 3% methanol 2500ml $68.9 2024-03-01 Buy
Alfa Aesar A15850 Methyl formate, 97%, may cont. up to ca 3% methanol 10000ml $187.65 2024-03-01 Buy
American Custom Chemicals Corporation CHM0118139 CARBOXYLIC ACID METHYL ESTER 95.00% 100ML $2347.13 2021-12-16 Buy
GFS CHEMICALS 16232 METHYLFORMATE,97% 500mL $94.32 2021-12-16 Buy
Medical Isotopes, Inc. 71434 Methyl Formate 100g $775 2021-12-16 Buy
Sigma-Aldrich 8.00889 Methyl formate for synthesis 100mL $32.6 2024-03-01 Buy
Sigma-Aldrich 8.00889 Methyl formate for synthesis 1L $51.2 2024-03-01 Buy
Sigma-Aldrich W519103 Methyl formate ≥95% sample $52 2022-05-15 Buy
Sigma-Aldrich 291056 Methyl formate anhydrous, 99% 100ml $77.1 2024-03-01 Buy
Sigma-Aldrich 06547 Methyl formate analytical standard 5ml $96.4 2024-03-01 Buy
Sigma-Aldrich 8.00889 Methyl formate for synthesis 2.5L $100 2024-03-01 Buy
Sigma-Aldrich M46837 Methyl formate reagent grade, 97% 1l $111 2024-03-01 Buy
Sigma-Aldrich 291056 Methyl formate anhydrous, 99% 1l $170 2024-03-01 Buy
Sigma-Aldrich M46837 Methyl formate reagent grade, 97% 4l $230 2024-03-01 Buy
Sigma-Aldrich 291056 Methyl formate anhydrous, 99% 2l $257 2024-03-01 Buy

Properties

Melting point :-100 °C (lit.)
Boiling point :32-34 °C (lit.)
Density :0.974 g/mL at 20 °C (lit.)
vapor density :2.1 (vs air)
vapor pressure :32.91 psi ( 55 °C)
refractive index :n20/D 1.343(lit.)
Flash point :−16 °F
storage temp. :Store below +30°C.
solubility :300g/l, 25% soluble in water, miscible with alcohol, Propylene glycol, Glycerin and oils.
form :Liquid
color :Clear colorless
PH :4-5 (200g/l, H2O, 20℃)
Odor :Pleasant; agreeable.
explosive limit :5-23%(V)
Odor Threshold :130ppm
Odor Type :fruity
Water Solubility :300 G/L (20 ºC)
λmax :λ: 259 nm Amax: 1.00
λ: 260 nm Amax: 0.70
λ: 265 nm Amax: 0.20
λ: 270 nm Amax: 0.04
λ: 310-400 nm Amax: 0.01 Merck :14,6077
BRN :1734623
Henry's Law Constant :0.90 at 5.00 °C, 1.18 at 10.00 °C, 1.51 at 15.00 °C, 1.91 at 20.00 °C, 2.36 at 25.00 °C (column stripping-UV, Kutsuna et al., 2005)
Exposure limits :TLV-TWA 100 ppm (~250 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 150 ppm (~375 mg/m3) (ACGIH); IDLH 5000 ppm (NIOSH).
Dielectric constant :8.5(20℃)
Stability :Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents.
LogP :-0.21 at 25℃
CAS DataBase Reference :107-31-3(CAS DataBase Reference)
NIST Chemistry Reference :Methyl formate(107-31-3)
EPA Substance Registry System :Methyl formate (107-31-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H224 Extremely flammable liquid and vapour Flammable liquids Category 1 Danger
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Description

Methyl formate is the methyl ester form of formic acid. It can be used for the manufacturing of fromamide, dimethylformamide, acetic acid and formic acid. It has been proposed to be a building block in C1 chemistry (processes that convert molecules with one carbon atom such as carbon monoxide, methanol, formaldehyde and methane into organic compounds with increased carbon number). It can also be used for quick-drying finishes and a blowing agent for some polyurethane foam due to its high vapor pressure. It can also be used as an insecticide.

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