TEBBE REAGENT
- $74.7 - $1120
- Product name: TEBBE REAGENT
- CAS: 67719-69-1
- MF: C13H4AlClTi
- MW: 270.47
- EINECS:
- MDL Number:MFCD00151575
- Synonyms:Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium;Chlorobishetacyclopentadienyldimethylammoniummumethyle;mu-Chlorobis(((heta)^5)-cyclopentadienyl)(dimethylammonium)-mu-methylene-titanium;Tebbe's reagent;μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum solution, 0.5M in toluene;BIS(CYCLOPENTADIENYL)-MU-CHLORO(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM;MU-CHLOROBIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM;MU-CHLOROBIS(ETA5-CYCLOPENTADIENYL)(DIMETHYLALUMINUM)-MU-METHYLENETITANIUM
6 prices
Selected condition:
Brand
- AK Scientific
- Alfa Aesar
- Sigma-Aldrich
Package
- 5mL
- 25ml
- 100ml
- 4x25ml
- ManufacturerAK Scientific
- Product numberH408
- Product descriptionTebbereagentsolution,0.5Mintoluene
- Packaging5mL
- Price$265
- Updated2021-12-16
- Buy
- ManufacturerAlfa Aesar
- Product number044506
- Product descriptionμ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
- Packaging5ml
- Price$74.7
- Updated2024-03-01
- Buy
- ManufacturerAlfa Aesar
- Product number044506
- Product descriptionμ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
- Packaging25ml
- Price$296
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number380237
- Product descriptionTebbe reagent solution 0.5 M in toluene
- Packaging25ml
- Price$296
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number380237
- Product descriptionTebbe reagent solution 0.5 M in toluene
- Packaging4x25ml
- Price$482
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number380237
- Product descriptionTebbe reagent solution 0.5 M in toluene
- Packaging100ml
- Price$1120
- Updated2024-03-01
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
AK Scientific | H408 | Tebbereagentsolution,0.5Mintoluene | 5mL | $265 | 2021-12-16 | Buy |
Alfa Aesar | 044506 | μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene | 5ml | $74.7 | 2024-03-01 | Buy |
Alfa Aesar | 044506 | μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene | 25ml | $296 | 2024-03-01 | Buy |
Sigma-Aldrich | 380237 | Tebbe reagent solution 0.5 M in toluene | 25ml | $296 | 2024-03-01 | Buy |
Sigma-Aldrich | 380237 | Tebbe reagent solution 0.5 M in toluene | 4x25ml | $482 | 2024-03-01 | Buy |
Sigma-Aldrich | 380237 | Tebbe reagent solution 0.5 M in toluene | 100ml | $1120 | 2024-03-01 | Buy |
Properties
Density :0.96 g/mL at 20 °C
Flash point :34 °F
storage temp. :Refrigerator
form :Solution
color :Dark red to purple
Water Solubility :Soluble in toluene, benzene, dichloromethane. Insoluble in water.
Sensitive :Air & Moisture Sensitive
Merck :9091
Exposure limits :ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) InChIKey :QEJAQNUJXFLWSP-UHFFFAOYSA-M
Flash point :34 °F
storage temp. :Refrigerator
form :Solution
color :Dark red to purple
Water Solubility :Soluble in toluene, benzene, dichloromethane. Insoluble in water.
Sensitive :Air & Moisture Sensitive
Merck :9091
Exposure limits :ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) InChIKey :QEJAQNUJXFLWSP-UHFFFAOYSA-M
Safety Information
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Description
μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.More related product prices
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$11-6700.45 - Nysted Reagent
$156-2543.02 - Potassium sodium tartrate
$25-499.05
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