77851-07-1 Basic information More..
Product Name:rose carboxylate
Synonyms:ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate;2-Cyclohexene-1-carboxylic acid, 2,3,6,6-tetramethyl-, ethyl ester;Ethyl-2,3,6,6-tetramethylcyclohex-2-en-1-carboxylat;2,3,6,6-Tetramethyl-2-cyclohexene-1-carboxylic acid ethyl ester;rose carboxylate
CAS:77851-07-1
MF:C13H22O2
MW:210.31
EINECS:278-776-7
Mol File:77851-07-1.mol
77851-07-1

Use

rose carboxylate is a mixture of isomers, bp0.8 kPa 102 °C, n20 D 1.4626, a colorless to pale yellow liquid with rosy, spicy, fruity, and woody odor. For its preparation, 3,6-dimethyl-6-hepten-2-one and 7-methyl-6-octen-3-one are treated with ethyl diethylphosphoryl acetate to give a mixture of octadienoic acid esters. Cyclization with sulfuric/formic acid yields the title compounds as a mixture with additional isomers. Owing to its complex odor, it is used in fine fragrances for shading.

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CAS:77851-07-1
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