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| (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Basic information | Reaction |
Product Name: | (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE | Synonyms: | (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE;(S,S)-NORPHOS;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene,min.95%(S,S)-NORPHOS;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE (S,S)-NORPHOS, (C 1,CHCL3);(1S,4R)-5α,6β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene;[[1R,4S,(+)]-Bicyclo[2.2.1]hept-5-ene-2α,3β-diyl]bis(diphenylphosphine);[[1R,4S,(+)]-Bicyclo[2.2.1]hepta-5-ene-2α,3β-diyl]bis(diphenylphosphine) | CAS: | 71042-54-1 | MF: | C31H28P2 | MW: | 462.5 | EINECS: | | Product Categories: | Chiral Phosphine;NORPhos Series;organophosphine ligand | Mol File: | 71042-54-1.mol | |
| (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Chemical Properties |
Melting point | 120 °C | alpha | +47° (c 1, CHCl3) | Boiling point | 577.0±50.0 °C(Predicted) | form | crystal | color | white | Sensitive | air sensitive | CAS DataBase Reference | 71042-54-1 |
| (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Usage And Synthesis |
Reaction |
- Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
- Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
- Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
| Chemical Properties | White crystalline powder |
| (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Preparation Products And Raw materials |
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