|
|
| | 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Basic information | | Uses |
| Product Name: | 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride | | Synonyms: | Dichloro [1,1'-bis(dicyclohexy;Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct, 99%;1,1′-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride 98%;1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride;Dichloro[1,1'-bis(dicyclohexylphosphiNA)ferrocene]palladiuM (II);[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladiuM(II);Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium (II);PalladiuM, [1,1'-bis(dicyclohexylphosphino-κP)ferrocene]dichloro-, (SP-4-2)- | | CAS: | 917511-90-1 | | MF: | 2C17H26P.Cl2Pd.Fe | | MW: | 755.904 | | EINECS: | | | Product Categories: | Pd | | Mol File: | 917511-90-1.mol |  |
| | 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Chemical Properties |
| Melting point | 294-300 °C | | storage temp. | -20°C | | form | Crystalline solid | | color | red-orange microcrystal | | InChI | InChI=1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2 | | InChIKey | HRAMBTUEZQOQRK-UHFFFAOYSA-L | | SMILES | [CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[Pd](Cl)Cl.[Fe] |^1:0,1,2,3,4,18,19,20,21,22| | | CAS DataBase Reference | 917511-90-1 |
| | 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Usage And Synthesis |
| Uses | 1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides.
| | Uses | 1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:
- α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
- Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.
- α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.
| | reaction suitability | core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
| | 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Preparation Products And Raw materials |
|