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| (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Basic information |
Product Name: | (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol | Synonyms: | (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol;Sparsiflorine;4H-Dibenzo[de,g]quinoline-1,10-diol, 5,6,6a,7-tetrahydro-2-methoxy-, (6aS)- | CAS: | 2128-61-2 | MF: | C17H17NO3 | MW: | 283.32 | EINECS: | | Product Categories: | | Mol File: | 2128-61-2.mol | ![(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Structure](CAS/GIF/2128-61-2.gif) |
| (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Chemical Properties |
Melting point | 230-232 °C (decomp) | Boiling point | 528.0±50.0 °C(Predicted) | density | 1.320±0.06 g/cm3(Predicted) | pka | 9?+-.0.20(Predicted) |
| (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Usage And Synthesis |
Description | The leaves of Croton sparsijlorus Morung yield this noraporphine alkaloid which
crystallizes as colourless, slender needles from EtOH. Two hydroxyl groups and
an imino group are present and the base yields crystalline salts and derivatives,
e.g. the hydrochloride, [α]30D + 43° (H20); methiodide, m.p. 218°C (dec.); the
O,N-diacetyl derivative, m.p. 245°C and the triacetyl derivative, m.p. 196-7°C.
The N-methyl compound gives a crystalline methiodide, m.p. 236-8°C (dec.).
The structure has been established as 2-methoxy-l : 10-dihydroxynor aporphine. | References | Chatterjee et al., Tetrahedron Lett., 1539 (1965) |
| (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Preparation Products And Raw materials |
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