|
| (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Basic information |
Product Name: | (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide | Synonyms: | (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide;(11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[
2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.;(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;SF110065;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d | CAS: | 864943-22-6 | MF: | C48H29O4P | MW: | 700.72 | EINECS: | | Product Categories: | | Mol File: | 864943-22-6.mol | ![(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Structure](CAS/20180808/GIF/864943-22-6.gif) |
| (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Chemical Properties |
Melting point | 390-400°C | density | 1.46±0.1 g/cm3(Predicted) | storage temp. | -20°C | pka | 1.11±0.20(Predicted) | optical activity | [α]22/D 44.0°, c = 1 in DMSO | CAS DataBase Reference | 864943-22-6 |
WGK Germany | 3 | HS Code | 2919900090 |
| (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Usage And Synthesis |
Uses | Catalyst for:
- Asymmetric hydrogenation cascade
- Enantioselective Friedel-Crafts reaction
- Asymmetric hydrogenation of 2-substituted quinolines
- Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
- Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
- Asymmetric transfer hydrogenation of substituted quinoxalines
|
| (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Preparation Products And Raw materials |
|