(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Suppliers list
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Company Name: Strem Chemicals, Inc.  
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Products Intro: Product Name:(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-i-Pr-DUPHOS-Rh
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Company Name: Advanced Technology & Industrial Co., Ltd.  
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(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information
Reaction
Product Name:(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms:(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(S,S)-I-PR-DUPHOS-RH;1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:
MF:C34H56BF4P2Rh
MW:716.47
EINECS:
Product Categories:Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes
Mol File:Mol File
(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Structure
(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties
Safety Information
MSDS Information
(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis
Reaction
  1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
  2. Forms superior catalysts for asymmetric reductive aminations.
  3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
  4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
  5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
  6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
  7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
  8. Palladium catalyzed asymmetric phosphination.
Reactions of (-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE_1
Reactions of (-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE_2
(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials
Tag:(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Related Product Information
Benzene (S,S)-I-PR-DUPHOS