DIETHYL (2-METHYLALLYL)PHOSPHONATE 97

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Products Intro: Product Name:Diethyl (2-Methylallyl)phosphonate
CAS:51533-70-1
Purity:97% Package:1G
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Products Intro: Product Name:Diethyl (2-methylallyl)phosphonate
CAS:51533-70-1
Purity:98% Remarks:SR01010100
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CAS:51533-70-1
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Products Intro: Product Name:Diethyl (2-methylallyl)phosphonate
CAS:51533-70-1
Purity:97% Package:1G Remarks:593095-1G
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Products Intro: Product Name:Diethyl (2-methylallyl)phosphonate
CAS:51533-70-1
Purity:98%;99% Package:50g;100g;500;1kg;5kg;10kg;25kg
DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Basic information
Product Name:DIETHYL (2-METHYLALLYL)PHOSPHONATE 97
Synonyms:Diethyl (2-methylallyl)phosphonate 97%;DIETHYL (2-METHYLALLYL)PHOSPHONATE 97;3-diethoxyphosphoryl-2-methylprop-1-ene;Phosphonic acid, P-(2-methyl-2-propen-1-yl)-, diethyl ester;Diethyl P-(2-methyl-2-propen-1-yl)phosphonate
CAS:51533-70-1
MF:C8H17O3P
MW:192.19
EINECS:
Product Categories:C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:51533-70-1.mol
DIETHYL (2-METHYLALLYL)PHOSPHONATE  97 Structure
DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Chemical Properties
Boiling point 62 °C/0.1 mmHg (lit.)
density 1.013 g/mL at 25 °C (lit.)
refractive index n20/D 1.4380(lit.)
Fp >230 °F
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 26
WGK Germany 3
MSDS Information
DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Usage And Synthesis
UsesDiethyl (2-methylallyl)phosphonate can be used as a reagent in the Horner-Wadsworth-Emmons reaction to form conjugated carbon–carbon double bonds.
It can also be used as a reactant for:
  • Enantioselective total synthesis of 10-isocyano-4-cadinene as antifouling agent.
  • Regiospecific preparation of 4-oxo-2-alkenylphosphonates (OAP) via silylation followed by Friedel-Crafts acylation and isomerization. OAP can serve as building blocks for the construction of polyethylenic chains.
  • The synthesis of azaphosphone as a potent analgesic/anti-inflammatory agents.

General DescriptionDiethyl (2-methylallyl)phosphonate is an organophosphorous compound. It participates in the synthesis of α-aminophosphonate derivatives and azaphosphones. The analgesic/antiinflammatory properties of these derivatives were evaluated.
DIETHYL (2-METHYLALLYL)PHOSPHONATE 97 Preparation Products And Raw materials
Preparation Products6,8-Nonadien-2-one, 8-methyl-5-(1-methylethyl)-, (5S,6E)-
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