(2R,6R)-2-methyl-6-prop-1-enyl-piperidine

(2R,6R)-2-methyl-6-prop-1-enyl-piperidine Basic information
Product Name:(2R,6R)-2-methyl-6-prop-1-enyl-piperidine
Synonyms:(2R,6R)-2-methyl-6-prop-1-enyl-piperidine;(-)-Pinidine;(2R)-2-Methyl-6α-[(E)-1-propenyl]piperidine;2α-Methyl-6α-[(E)-1-propenyl]piperidine;Pinidine;Piperidine, 2-methyl-6-(1E)-1-propen-1-yl-, (2R,6R)-
CAS:501-02-0
MF:C9H17N
MW:139.24
EINECS:
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Mol File:501-02-0.mol
(2R,6R)-2-methyl-6-prop-1-enyl-piperidine Structure
(2R,6R)-2-methyl-6-prop-1-enyl-piperidine Chemical Properties
Boiling point 176-7oC/751mm
density 0.879±0.06 g/cm3(Predicted)
pka10.30±0.10(Predicted)
Safety Information
MSDS Information
(2R,6R)-2-methyl-6-prop-1-enyl-piperidine Usage And Synthesis
DescriptionA piperidine alkaloid isolated from Pinus jeffreyi, P. sabiniana Doug!., and P. torreyana, this base is a colourless liquid which is laevorotatory with [Ql~~9 - 10.5° and [Ql~j5 - 23.4° (c 1.88, EtOH). It yields a crystalline hydrochloride as colourless needles from EtOH-AcOEt, m.p. 244-6°C and a methiodide, m.p. 214-8°C. The structure has been determined by spectroscopic methods as 2-methyl-6-( trans-2-propeny I)-piperidine.
DefinitionChEBI: Pinidine is a piperidine alkaloid.
ReferencesTallent, Stromberg, Horning.,J. Arner. Chern. Soc., 77,6361 (1955)
Tallent, Horning., ibid, 78,4467 (1956)
Hill, Chan, Joule., Tetrahedron, 21,147 (1965)
(2R,6R)-2-methyl-6-prop-1-enyl-piperidine Preparation Products And Raw materials
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