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Shanghai Daken Advanced Materials Co.,Ltd |
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+86-371-66670886 |
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| Products Intro: |
Product Name:4-{2-[(3R,5S,7s)-adamantan-1-yl(1s,3R,5S,7s)-adamantan-1-ylphosphanyl]phenyl}morpholine
CAS:1237588-12-3
Purity:99% Package:1mg,10gm,1g,5g,10g
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| | N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Basic information | | Reaction |
| | N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Chemical Properties |
| Melting point | 219-224°C | | storage temp. | 2-8°C | | form | crystal | | pka | 4.75±0.40(Predicted) | | color | white to yellow | | Sensitive | air sensitive | | CAS DataBase Reference | 1237588-12-3 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 |
| | N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Usage And Synthesis |
| Reaction |
- P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
- P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
- P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.
| | Uses | Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates. | | Uses | MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone. |
| | N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Preparation Products And Raw materials |
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