Company Name: |
Daicel Chiral Technologies (China)CO.,LTD
|
Tel: |
021-50460086-9 15921403865 |
Email: |
han_yajun@dctc.daicel.com |
Products Intro: |
Product Name:1-Fluoro-methanesulfinic Acid Sodium (1:1) CAS:1661836-10-7 Purity:95%/98% Package:1G;100G; 1KG Remarks:(Component:1416941-77-9)201200
|
|
| Sodium fluoromethanesulfinate Basic information |
Product Name: | Sodium fluoromethanesulfinate | Synonyms: | Sodiumfluoromethanesulfinate;Methanesulfinic acid, 1,1-difluoro-, sodium salt (1:1);Methanesulfinic acid, 1-fluoro-, sodium salt;fluoromethanesulfinic acid, sodium salt | CAS: | 1661836-10-7 | MF: | CH2FNaO2S | MW: | 120.0785532 | EINECS: | | Product Categories: | | Mol File: | 1661836-10-7.mol | ![Sodium fluoromethanesulfinate Structure](CAS/20180527/GIF/1661836-10-7.gif) |
| Sodium fluoromethanesulfinate Chemical Properties |
| Sodium fluoromethanesulfinate Usage And Synthesis |
Uses | Sodium fluoromethanesulfinate is used as efficient radical fluoroalkylating reagents,it is able to react with conjugated N-arylsulfonated amides to yield the desired fluoroalkylamides.
| Reactions | ![Methanesulfinic acid, 1,1-difluoro-, sodium salt (1:1) Methanesulfinic acid, 1,1-difluoro-, sodium salt (1:1)](/NewsImg/2024-01-22/6384152755188612119752455.png) Ref. 1) He, Z.; Tan, P.; Ni, C.; Hu, J. Org. Lett. 2015, 17, 1838 –1841. (The invention of HCF2SO2Na and H2CFSO2Na as radical fluoroalkylation reagents)
2) Dai, P.; Yu, X.; Teng, P.; Zhang, W.-H.; Deng, C. Org. Lett. 2018, 20, 6901-6905.
3) Zhang, W. et al. Nat. Commun. 2020, 11, art. no. 638. (HCF2SO2Na was referred to as Hu’s reagent) |
| Sodium fluoromethanesulfinate Preparation Products And Raw materials |
|