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Aladdin Scientific |
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+1-+1(833)-552-7181 |
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sales@aladdinsci.com |
Products Intro: |
Product Name:(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate CAS:903571-02-8 Purity:>98.0%(HPLC) Package:$64.9/25mg;$197.9/100mg;$444.9/250mg;$1600.9/1g;Bulk package Remarks:>98.0%(HPLC)
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Company Name: |
J & K SCIENTIFIC LTD.
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Tel: |
010-82848833 400-666-7788 |
Email: |
jkinfo@jkchemical.com |
Products Intro: |
Product Name:(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride, 98% CAS:903571-02-8 Purity:98% Package:100MG;1G;250MG
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| Bode Catalyst 2 Basic information |
Product Name: | Bode Catalyst 2 | Synonyms: | (5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate;Bode Catalyst 2;(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride;(+)-(5aR,10bS)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
Bode Catalyst 2;(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride (+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate;[5a-R,10b-S]-2-(2,4,6-Trimethyl-phenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azonia-cyclopenta[c]fluorene chloride;(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-triMethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo | CAS: | 903571-02-8 | MF: | C21H22ClN3OH2O | MW: | 0 | EINECS: | | Product Categories: | | Mol File: | 903571-02-8.mol | ![Bode Catalyst 2 Structure](CAS/GIF/903571-02-8.gif) |
| Bode Catalyst 2 Chemical Properties |
Melting point | 226-230 °C | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | form | powder to crystal | color | White to Gray to Red | optical activity | [α]20/D +158°, c = 1 in chloroform |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26 | WGK Germany | 3 | HS Code | 29349990 |
| Bode Catalyst 2 Usage And Synthesis |
Uses | (5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as a catalyst:
- In the preparation of dihydropyridinones by reacting enals or α′-hydroxyenones with vinylogous amides via aza-Claisen annulations.
- In the oxidative coupling reactions of di(hetero)arylmethanes with enals to yield benzimidazole fused lactams.
- In the synthesis of organosilanes by reacting enals with β-silyl enones.
| General Description | It is an N-mesityl-substituted chiral triazolium N-heterocyclic carbene (NHC) compound. It was developed as an organocatalyst by the Bode group, for the catalytic generation of reactive species including activated carboxylates, homoenolates, and enolates. |
| Bode Catalyst 2 Preparation Products And Raw materials |
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