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| | 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Basic information |
| Product Name: | 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine | | Synonyms: | 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine;Spiradine G;12aH,14H-3,14a-Ethano-14,4b,8-ethanylylidene-1H,5H-[2]benzopyrano[4,3-g]oxazolo[3,2-a]azocin-17-ol, decahydro-8-methyl-2-methylene-, (3S,4aR,4bR,8R,8aR,12aS,14S,14aR,17S,18R)- (9CI) | | CAS: | 21040-66-4 | | MF: | C22H31NO3 | | MW: | 357.49 | | EINECS: | | | Product Categories: | | | Mol File: | 21040-66-4.mol |  |
| | 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Chemical Properties |
| | 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Usage And Synthesis |
| Description | A sixth alkaloid found in Spiraea japonica L. fil., the base is laevorotatory with
[α]D - 137° (c 1.16, MeOH). Reduction with NaBH4 gives a triol while oxida_x0002_tion with chromic acid in pyridine forms a monoketone, m.p. IS8-l60°C. The
presence of an exocyclic methylene group is confirmed by catalytic reduction
and subsequent oxidation with KMn04 to give a ketone. | | References | Toda, Hirata., Tetrahedron Lett., 5565 (1968) |
| | 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Preparation Products And Raw materials |
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