15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine

15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Suppliers list
Company Name: PUZHIYUAN BIOTECHNOLOGY Co LTD  
Tel: 13985734807 13985734807
Email: 15208534140@163.cn
Products Intro: Product Name:Spiradin G
CAS:21040-66-4
Purity:200% HPLC
15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Basic information
Product Name:15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine
Synonyms:15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine;Spiradine G;12aH,14H-3,14a-Ethano-14,4b,8-ethanylylidene-1H,5H-[2]benzopyrano[4,3-g]oxazolo[3,2-a]azocin-17-ol, decahydro-8-methyl-2-methylene-, (3S,4aR,4bR,8R,8aR,12aS,14S,14aR,17S,18R)- (9CI);Spiradin G
CAS:21040-66-4
MF:C22H31NO3
MW:357.49
EINECS:
Product Categories:
Mol File:21040-66-4.mol
15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Structure
15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Chemical Properties
Melting point 168-l700 C
Safety Information
MSDS Information
15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Usage And Synthesis
DescriptionA sixth alkaloid found in Spiraea japonica L. fil., the base is laevorotatory with [α]D - 137° (c 1.16, MeOH). Reduction with NaBH4 gives a triol while oxida_x0002_tion with chromic acid in pyridine forms a monoketone, m.p. IS8-l60°C. The presence of an exocyclic methylene group is confirmed by catalytic reduction and subsequent oxidation with KMn04 to give a ketone.
ReferencesToda, Hirata., Tetrahedron Lett., 5565 (1968)
15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Preparation Products And Raw materials
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