Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

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CAS:27057-09-6
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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Basic information
Reaction
Product Name:Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Synonyms:Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II);BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99%;Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%;2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide;Bis(triphenylphosphino)(2-methylphenyl)chloronickel;Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride
CAS:27057-09-6
MF:C43H39ClNiP2
MW:711.88
EINECS:
Product Categories:
Mol File:27057-09-6.mol
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Structure
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Chemical Properties
Melting point 195-200°C
storage temp. 2-8°C
form Powder
color yellow
CAS DataBase Reference27057-09-6
Safety Information
WGK Germany 3
MSDS Information
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Usage And Synthesis
Reaction
  1. This complex is used as an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates.
  2. This nickel precatalyst is used for the polymerization of halothiophenes. 
Reactions of 27057-09-6
UsesProduct is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Preparation Products And Raw materials
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