(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine Suppliers list
Company Name: Aladdin Scientific
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine
CAS:1173836-08-2
Purity:97% Package:$98.9/250mg;$296.9/1g;Bulk package Remarks:97%
Company Name: Shanghai Anyinuo Biomedical Technology Co., Ltd.  Gold
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine
CAS:1173836-08-2
Purity:>=98% Package:100mg;250mg;500mg;1g;10g;100g;1kg
Company Name: LaaJoo  
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine
CAS:1173836-08-2
Purity:97% Package:100mg
Company Name: Shanghai Hao Zhun Biological Technology Co., Ltd.  
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine, min. 97% (S,R)-N-PINAP
CAS:1173836-08-2
Purity:min. 97%
Company Name: Strem Chemicals, Inc.  
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine, min. 97% (S,R)-N-PINAP
CAS:1173836-08-2
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine Basic information
Reaction
Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine
Synonyms:(R)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(1S)-1-PHENYLETHYL]-1-PHTHALAZINAMINE;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(S)-1-PHENYLETHYL]-1-PHTHALAZINAMINE,MIN.97%(S,R)-N-PINAP;1-Phthalazinamine, 4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1S)-1-phenylethyl]-, (1R)-
CAS:1173836-08-2
MF:C38H30N3P
MW:559.64
EINECS:
Product Categories:Chiral Phosphine;PINAP Series
Mol File:1173836-08-2.mol
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine Structure
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine Chemical Properties
Melting point >210°C
form crystal
color colorless
Sensitive air sensitive
Safety Information
MSDS Information
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine Usage And Synthesis
Reaction
  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
  2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
  3. With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
Reactions of 1173836-08-2
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine Preparation Products And Raw materials
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