AdBrettPhos Pd G3

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Products Intro: Product Name:AdBrettPhosPdG3
CAS:1445972-29-1
Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;1652T/drum;
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Products Intro: Product Name:AdBrettPhos Palladacycle Gen. 3
CAS:1445972-29-1
Purity:0.99 Package:25KG;5KG;1KG
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Products Intro: Product Name:AdBrettPhosPdG3
CAS:1445972-29-1
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Products Intro: Product Name:Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...
CAS:1445972-29-1
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Products Intro: Product Name:DI-AD-BRETTPHOS-G3-PALLADACYCLE
CAS:1445972-29-1
Package:1g; 5g; 25g; 1kg; 5kg; 25kg
AdBrettPhos Pd G3 Basic information
Reaction
Product Name:AdBrettPhos Pd G3
Synonyms:METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3];Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);AdBrettPhos Palladacycle Gen. 3;bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3;AdBrettPhos Pd G3;bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
CAS:1445972-29-1
MF:C56H74NO5PPdS
MW:1010.66
EINECS:
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Mol File:1445972-29-1.mol
AdBrettPhos Pd G3 Structure
AdBrettPhos Pd G3 Chemical Properties
Melting point 251-253 °C
form solid
color brown to green
Safety Information
MSDS Information
AdBrettPhos Pd G3 Usage And Synthesis
ReactionPalladium catalyst used in the highly selective monoarylation of ammonia. Reactions of 1445972-29-1
UsesBuchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts
AdBrettPhos Pd G3 Preparation Products And Raw materials
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