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| | Chlorobis(cyclooctene)rhodium(I) dimer Basic information |
| | Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties |
| Melting point | 190 °C (dec.) (lit.) | | storage temp. | Freezer | | form | crystal | | color | orange to red | | Sensitive | air sensitive, store cold | | CAS DataBase Reference | 12279-09-3 |
| | Chlorobis(cyclooctene)rhodium(I) dimer Usage And Synthesis |
| Chemical Properties | orange-brown powder | | Uses | Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO. | | Uses | Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
- To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
- In direct C-arylation of N-unprotected indoles and pyrroles.
- In the carboxylation of arenes via C-H bond activation.
| | reaction suitability | core: rhodium
reagent type: catalyst |
| | Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials |
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