Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride

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Products Intro: Product Name:Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride
CAS:2055837-32-4
Purity:95% Package:$130.9/100mg;Bulk package Remarks:95%
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Products Intro: Product Name:Bis(triphenyl-lambda5-phosphanylidene)ammonium hydrogendifluoride
CAS:2055837-32-4
Purity:Bis(triphenyl-lambda5-phosphanylidene)ammonium hydrogendiflu Package:250MG Remarks:901741-250MG
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Products Intro: Product Name:Triphenyl[(triphenylphosphoranylidene)amino]phosphonium Fluoride Hydrofluoride
CAS:2055837-32-4
Purity:>=95% Package:0.25g
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Products Intro: Product Name:Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride
CAS:2055837-32-4
Purity:95% Package:100mg/RMB 2999.90;250mg/RMB 1876.90
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Products Intro: Product Name:Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride
CAS:2055837-32-4
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Basic information
Product Name:Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride
Synonyms:Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride;Bis(triphenyl-lambda5-phosphanylidene)ammonium hydrogendifluoride;Triphenyl[(triphenylphosphoranylidene)amino]phosphonium Fluoride Hydrofluoride
CAS:2055837-32-4
MF:C36H31F2NP2
MW:577.6
EINECS:
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Mol File:2055837-32-4.mol
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Structure
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Chemical Properties
storage temp. 2-8°C
Safety Information
MSDS Information
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Usage And Synthesis
UsesBifluoride salt reported by K. Barry Sharpless and colleagues as a catalyst for sulfur(VI) fluoride exchange (SuFEx)-based AA-BB polycondensation reactions to prepare polysulfonates with diverse structures, narrow polydispersity, and excellent thermal and hydrolytic stability. Bisalkylsulfonyl fluorides, the AA monomers, were prepared from ethenesulfonyl fluoride (746959) and amines/anilines while bisphenol bis(t-butyldimethylsilyl) ethers, the BB monomers, were synthesized using tert-butyldimethylsilyl chloride (190500) and bisphenols. Varying the amines, anilines, and bisphenols results in assorted polymeric backbones, including those bearing orthogonal side chains for modification post-polymerization (e.g. by CuAAC). Reaction is amenable to scale up.
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Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Preparation Products And Raw materials
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