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Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct

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Company Name: CONIER CHEM AND PHARMA LIMITED
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Products Intro: CAS:137203-34-0
Purity:99% Package:1kg
Company Name: Antai Fine Chemical Technology Co.,Limited
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Products Intro: Product Name:DABAL-Me3 (adduct of trimethylaluminum and DABCO)
CAS:137203-34-0
Purity:0.98 Package:1KG;5KG;25KG
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Products Intro: Product Name:Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
CAS:137203-34-0
Purity:95% Min. Package:100g; 500g; 1kg; 25kg;bulk package
Company Name: Dayang Chem (Hangzhou) Co.,Ltd.
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Products Intro: Product Name:Bis(Trimethylaluminum)-1,4-Diazabicyclo[2.2.2]Octane Adduct
CAS:137203-34-0
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Hot sales
Company Name: Hangzhou MolCore BioPharmatech Co.,Ltd.
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Products Intro: Product Name:Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum)
CAS:137203-34-0
Purity:NLT 98% Package:1G;100G;1KG;50KG Remarks:MC824211
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Basic information
Product Name:Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
Synonyms:Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct;Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum);DABAL-trimethylaluminum;Bis(trimethylaluminum)-DABCO(R) adduct;Triethylenediaminine bis(trimethylaluminum);Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octane adduct (DABAL-Me3);DABAL-Me3 (adduct of trimethylaluminum and DABCO);1,4-DIAZABICYLO[2.2.2]OCTANE BIS(TRIMETHYLALUMINUM) COMPLEX
CAS:137203-34-0
MF:C12H24Al2N2
MW:250.3
EINECS:
Product Categories:Greener Alternatives and Technologies;Greener Alternatives: Reagents;DABAL - Me3;Chemical Synthesis;Organoaluminum;Organometallic Reagents
Mol File:137203-34-0.mol
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Structure
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Chemical Properties
Melting point >250 °C
Fp 23°C (73°F)
storage temp. Hygroscopic, Room Temperature, Under inert atmosphere
solubility Benzene (Slightly), DMSO (Slightly)
form Solid
color White to Off-White
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Stability:Hygroscopic, Moisture Sensitive, Unstable in Aqueous Solution
Safety Information
Hazard Codes F,Xn
Risk Statements 14-15-22-36/37/38
Safety Statements 16-26-43
RIDADR UN 3395 4.3/PG 1
WGK Germany 3
MSDS Information
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Usage And Synthesis
UsesDABAL-Me3: An Air Stable "Methyl Anion"
UsesBis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum) is a non-pyrophoric alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation.1
General DescriptionProduct is air and moisture sensitive. Handle and store under a dry, inert atmosphere.
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Preparation Products And Raw materials
Preparation Products1-Cyclopentene-1-carboxylic acid, 2-methyl-, ethyl ester
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