13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine

13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Basic information
Product Name:13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine
Synonyms:13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine;Methoxychelidonine
CAS:
MF:C20H15NO6
MW:365.3362
EINECS:
Product Categories:
Mol File:Mol File
13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Structure
13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Chemical Properties
Melting point 221°C
Safety Information
MSDS Information
13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Usage And Synthesis
DescriptionThis alkaloid has been obtained by Gadamer and Winterfeld during a systematic examination of the residues remaining after the isolation of chelidonine from Chelidonum majus L. The base forms colourless prisms on crystallization from EtOH and has [α]D + 115.8°. It furnishes a crystalline hydrochloride and an aurichloride, m.p. 237-8°C. The O-acetate is amorphous, m.p. 147°C; [α]D + 55.5°. One methoxyl group, two methylenedioxy groups, one hydroxyl group and a methylimino group are present in the molecule.
ReferencesGadamer, Winterfeld., Arch. Pharm., 257,298 (1919)
Garlamer, Winterfeld., ibid, 258, 148 (1920)
Gadamer, Winterfeld., ibid, 262,249 (1924)
Bruchhausen, Bersch., Ber., 63,2520 (1930)
Bruchhausen, Bersch., ibid, 64,370 (1931)
13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Preparation Products And Raw materials
Tag:13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Related Product Information
Phenanthridine