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| (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Basic information |
Product Name: | (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline | Synonyms: | (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline;Lycodine;1H-5,10b-Propano-1,7-phenanthroline, 2,3,4,4a,5,6-hexahydro-12-methyl-, (4aR,5S,10bR,12R)- | CAS: | 20316-18-1 | MF: | C16H22N2 | MW: | 242.36 | EINECS: | | Product Categories: | | Mol File: | 20316-18-1.mol | ![(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Structure](CAS/20180808/GIF/20316-18-1.gif) |
| (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Chemical Properties |
Melting point | 118-119° | alpha | D -10° (c = 1.01 in ethanol) | pka | 3.97, 8.08(at 25℃) |
| (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Usage And Synthesis |
Description | One of the numerous alkaloids obtained from the various Lycopodium species,
this base has been found in L. annotinurn L. and L. fawcettii. It forms colourless
crystals and has [α]D - 10° ± 2° (c 1.01, EtOH). One of the nitrogen atoms is
present in a pyridine ring, the other being in the form of an imino group. The
picrate is obtained as prisms from MeOH and has m.p. 229-233°C. | Definition | ChEBI: Lycodine is a phenanthrol. | References | Anet, Eves., Can. J. Chern., 36,902 (1958)
Anet, Rao., Tetrahedron Lett., No. 20, 9 (1960)
Burnell et al., Can. J. Chern., 41, 3091 (1963) |
| (4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Preparation Products And Raw materials |
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