rugulovasine A

rugulovasine A Basic information
Product Name:rugulovasine A
Synonyms:rugulovasine A;RUGULOVASINA;Spiro[benz[cd]indole-5(1H),2'(5'H)-furan]-5'-one, 3,4-dihydro-4'-methyl-4-(methylamino)-, (2'R,4S)-rel-
CAS:26909-33-1
MF:C16H16N2O2
MW:268.31
EINECS:
Product Categories:
Mol File:26909-33-1.mol
rugulovasine A Structure
rugulovasine A Chemical Properties
Melting point 138° (dec)
alpha 22436 -3.0° (pyridine)
Safety Information
MSDS Information
rugulovasine A Usage And Synthesis
DescriptionA non-crystallizable alkaloid, this base has been obtained from cultures of Penicillium concavorugulosum. It is slightly laevorotatory with [α]22436 - 3.0° (c 1.0, pyridine). The five-membered lactone ring is unsaturated and on catalytic hydrogenation the alkaloid forms the crystalline dihydro derivative, m.p. l49-l5l oC. One of the nitrogen atoms is present in the indole ring, the other being a methylamino group.
ReferencesAbe et al., Agr. Bioi. Chern., (Tokyo), 33, 469 (1969)
Abe et al., Nippon Nogeikagaku Kaishi, 43, 575 (1969)
Yamatodani et al., Agr. Bioi. Chern., (Tokyo), 34,485 (1970)
rugulovasine A Preparation Products And Raw materials
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