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ethyl 4,4,4-trifluorobut-2-enoate

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ethyl 4,4,4-trifluorobut-2-enoate Suppliers list
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: 0551-65418671
Email: sales@tnjchem.com
Products Intro: Product Name:2-Butenoic acid,4,4,4-trifluoro-, ethyl ester
CAS:406-10-0
Company Name: Anichem Inc.  
Tel: 0512-69369885
Email: sales@anichem.com.cn
Products Intro: Product Name:ETHYL 4,4,4-TRIFLUOROCROTONATE
CAS:406-10-0
Purity:>97% Package:5g;25g;50g;100g;250g;500g
Company Name: Shanghai Tombiopharma Chemical Co. Ltd.  
Tel: 13391076197
Email: tombiopharma@163.com
Products Intro: Product Name:ethyl 4,4,4-trifluorobut-2-enoate
CAS:406-10-0
Purity:97% HPLC Package:10g;100g;1kg;10kg
Company Name: Sigma-Aldrich  
Tel: 021-61415566 800-8193336
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Products Intro: Product Name:Ethyl 4,4,4-trifluorocrotonate
CAS:406-10-0
Company Name: Zhengzhou Huiju Chemical Co., Ltd.  
Tel: 0371-55900031 18137872243
Email: 2853979815@qq.com
Products Intro: Product Name:Ethyl 4,4,4-trifluorocrotonate
CAS:406-10-0
Purity:98% Package:1g ；5g ；10g ；25g ；100g ；500g ；1kg ；5kg
ethyl 4,4,4-trifluorobut-2-enoate Basic information
Product Name:ethyl 4,4,4-trifluorobut-2-enoate
Synonyms:ethyl 4,4,4-trifluorobut-2-enoate;2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester;4,4,4-trifluoro-2-Butenoic acid ethyl ester
CAS:406-10-0
MF:C6H7F3O2
MW:168.11
EINECS:
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Mol File:406-10-0.mol
ethyl 4,4,4-trifluorobut-2-enoate Structure
ethyl 4,4,4-trifluorobut-2-enoate Chemical Properties
density 1.125 g/mL at 25 °C(lit.)
refractive index n20/D 1.3601(lit.)
Fp 26°C
Boiling point 114-115°C(lit.)
Safety Information
RIDADR UN 3272 3 / PGIII
WGK Germany 3
MSDS Information
ethyl 4,4,4-trifluorobut-2-enoate Usage And Synthesis
UsesEthyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate.
General DescriptionThe Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied.
ethyl 4,4,4-trifluorobut-2-enoate Preparation Products And Raw materials
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