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(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP

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(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
CAS:828927-95-3
Purity:min. 97% Package:1g;250mg
Company Name: Bide Pharmatech Ltd.  
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Products Intro: Product Name:(R)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine
CAS:828927-95-3
Purity:98% Package:100mg;250mg;1g;
Company Name: LaaJoo  
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Products Intro: Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine
CAS:828927-95-3
Purity:97% Package:100mg
Company Name: Shanghai Anyinuo Biomedical Technology Co., Ltd.  
Tel: 021-34625901
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Products Intro: Product Name:(R,R)-O-PINAP
CAS:828927-95-3
Purity:>=98% Package:100mg;250mg;500mg;1g;10g;100g;1kg
Company Name: Energy Chemical  
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Products Intro: CAS:828927-95-3
Purity:97% Package:1g;250mg Remarks:NULL
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Basic information
Reaction
Product Name:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
Synonyms:(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP;(R,R)-O-PINAP;Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1R)-
CAS:828927-95-3
MF:C38H29N2OP
MW:560.62
EINECS:
Product Categories:PINAP Series;Chiral Phosphine
Mol File:828927-95-3.mol
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Structure
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Chemical Properties
Melting point 64-65°C
alpha +78.5° (c 0.25, CHCl3)
Boiling point 726.4±60.0 °C(Predicted)
pka3.45±0.30(Predicted)
form crystal
color colorless
Sensitive air sensitive
Safety Information
MSDS Information
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Usage And Synthesis
Reaction
  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
  2. With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
  3. With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
Reactions of 828927-95-3
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Preparation Products And Raw materials
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