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Energy Chemical
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Product Name:Tris(triMethylsilyl)silyl vinyl ether
CAS:861445-91-2
Package:500MG
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696 |
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Product Name:Tris(trimethylsilyl)silyl vinyl ether
CAS:861445-91-2
Purity:98% Remarks:MR040277
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Sigma-Aldrich
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021-61415566 800-8193336 |
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| Products Intro: |
Product Name:Tris(trimethylsilyl)silyl vinyl ether
CAS:861445-91-2
Purity:NULL Package:500MG Remarks:Aldrich
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| Company Name: |
Riedel-de Haen AG
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800 558-9160 |
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| Products Intro: |
CAS:861445-91-2
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| | Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Basic information |
| Product Name: | Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane | | Synonyms: | Tris(trimethylsilyl)silyl vinyl ether;Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane;Trisilane, 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-;2-(Ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane | | CAS: | 861445-91-2 | | MF: | C11H30OSi4 | | MW: | 290.7 | | EINECS: | | | Product Categories: | | | Mol File: | 861445-91-2.mol |  |
| | Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Chemical Properties |
| Melting point | 51-61 °C | | Fp | 78 °C | | storage temp. | 2-8°C |
| | Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Usage And Synthesis |
| Uses | Super Silyl Protecting Groups
Used for:
- Diastereoselective [2+2] cyclizations
- Cross-Aldol cascade reaction
- Diastereoselective sequential reactions for generating polyols
- Accessing distinct diastereomers and 4-component reactions
- Supersilyl-directed aldol reactions
- Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position
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| | Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Preparation Products And Raw materials |
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