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Nanchang Zhenshi Biotechnology Co., Ltd Gold
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Product Name:Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
CAS:863971-62-4
Purity:95% Package:100mg;250mg;500mg;1g
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| Company Name: |
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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jkinfo@jkchemical.com |
| Products Intro: |
Product Name:Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
CAS:863971-62-4
Purity:min. 98% Package:100mg;500mg
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| | Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Basic information | | Reaction |
| Product Name: | Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) | | Synonyms: | Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)
pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Milstein Catalyst Precursor;Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% | | CAS: | 863971-62-4 | | MF: | C20H37ClN2OPRu | | MW: | 489.02 | | EINECS: | | | Product Categories: | Ru;organometallic complex | | Mol File: | 863971-62-4.mol | ![Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Structure](CAS/20211123/GIF/863971-62-4.gif) |
| | Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Chemical Properties |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | solid | | color | pale yellow | | Sensitive | air sensitive |
| Hazard Codes | Xn | | Risk Statements | 19-40 | | Safety Statements | 36/37 | | WGK Germany | 3 |
| | Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Usage And Synthesis |
| Reaction |
- Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
- Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
- Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
- Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.
- Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone
| | Uses | Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2 | | General Description | May contain up to 10% acetone and/or THF. | | reaction suitability | core: ruthenium
reagent type: catalyst |
| | Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Preparation Products And Raw materials |
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