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Sigma-Aldrich
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Product Name:Alcohol Togni-(PhSCF2CF2)-reagent
CAS:1836233-11-4
Purity:Alcohol Togni-(PhSCF2CF2)-reagent Package:250MG Remarks:CF0004-250MG
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| Company Name: |
Dalian Shuanghang Chemical Co., LTD
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+86-411-66858498 +86-13941194417 |
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Product Name:3,3-Dimethyl-1-(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole
CAS:1836233-11-4
Package:1ASSAYS
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| Company Name: |
Merck KGaA
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21-20338288 |
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ordercn@merckgroup.com |
| Products Intro: |
Product Name:Alcohol Togni-(PhSCF2CF2)-reagent
CAS:1836233-11-4
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| | Alcohol Togni-(PhSCF2CF2)-reagent Basic information |
| Product Name: | Alcohol Togni-(PhSCF2CF2)-reagent | | Synonyms: | Alcohol Togni-(PhSCF2CF2)-reagent;1,2-Benziodoxole, 1,3-dihydro-3,3-dimethyl-1-[1,1,2,2-tetrafluoro-2-(phenylthio)ethyl]-;3,3-Dimethyl-1-(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole;Alcohol Togni-(PhSCF2CF2)-reagent | | CAS: | 1836233-11-4 | | MF: | C17H15F4IOS | | MW: | 470.26 | | EINECS: | | | Product Categories: | | | Mol File: | 1836233-11-4.mol |  |
| | Alcohol Togni-(PhSCF2CF2)-reagent Chemical Properties |
| storage temp. | -20°C | | form | solid |
| | Alcohol Togni-(PhSCF2CF2)-reagent Usage And Synthesis |
| Uses | Alcohol Togni-(PhSCF2CF2)-reagent is an electrophilic hypervalent iodine-fluoroalkyl reagent introducing the phenylsulfanyltetrafluoroethyl fragment. A phenylsulfanyltetrafluoroethyl moiety incorporated in the substrate can be treated with tributyltin hydride and generate the corresponding fluoroalkyl radical. If the substrate lacks any olefine, it can be reduced to tetrafluoroethyl group whereas if the substrate contains an olefine in the correct spatial orientation, it can lead to an intramolecular cyclisation affording tetrafluorinated cyclic structures. | | reaction suitability | reaction type: C-C Bond Formation |
| | Alcohol Togni-(PhSCF2CF2)-reagent Preparation Products And Raw materials |
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