Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride

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Products Intro: Product Name:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
CAS:1033772-47-2
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CAS:1033772-47-2
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Products Intro: Product Name:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
CAS:1033772-47-2
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC10044
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Products Intro: Product Name:Bis[(2-diMethylaMino)phenyl]aMine Nickel(II) Chloride
CAS:1033772-47-2
Package:100Mg,1g
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Products Intro: Product Name:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
CAS:1033772-47-2
Purity:97.00% Package:500mg;100mg
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Basic information
Product Name:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
Synonyms:Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride;Bis[(2-diMethylaMino)phenyl]aMine nickel(II) chloride,98%;(SP-4-3)-Chloro[N2-[2-(diMethylaMino-κN)phenyl]-N1,N1-diMethyl-1,2-benzenediaMinato-κN1,κN2]nickel;Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride >=97% (AT);Bis[(2-dimethylamino)phenyl]aminenickel(II)chloride>=98.0%(AT);]amine nickeL;Nickamine
CAS:1033772-47-2
MF:C16H20ClN3Ni
MW:348.5
EINECS:
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Mol File:1033772-47-2.mol
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Structure
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Chemical Properties
form Solid
Safety Information
WGK Germany 3
MSDS Information
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Usage And Synthesis
UsesBis[(2-dimethylamino)phenyl]amine Nickel(II) Chloride is a new pincer-type bis(amido)amine (NN2) ligand. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C cou pled products and Ni(II) halides.
UsesCatalyst for:
  • Alkyl-alkyl Kumada coupling of secondary alkyl halides
  • Direct alkylation of heterocyclic C-H bonds
  • Sonogashira coupling of nonactivated alkyl halides
  • Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles

Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride Preparation Products And Raw materials
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