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Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos]

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Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Suppliers list
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Products Intro: Product Name:1025477-38-6
CAS:1025477-38-6
Purity:0.99 Package:1KG;25KG
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Products Intro: Product Name:Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-Methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}rutheniuM(II) Ru(OAc)2[(R)-dtbM-segphos?]
CAS:1025477-38-6
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Products Intro: Product Name:RU(OAC)2[(R)-DTBM-SEGPHOS
CAS:1025477-38-6
Purity:98% Package:1g;10g;100g;1000g
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Products Intro: Product Name:Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-Methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}rutheniuM(II)
CAS:1025477-38-6
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Products Intro: Product Name:Ru(OAc)2[(R)-dtbm-segphos
CAS:1025477-38-6
Purity:97% Package:250mg
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Basic information
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Product Name:Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos]
Synonyms:Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos];Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos(R)];Ru(OAc)2[(R)-dtbm-segphos];Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyL;e}ruthenium(II);Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II)
CAS:1025477-38-6
MF:C78H108O12P2Ru
MW:1400.73
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Mol File:1025477-38-6.mol
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Structure
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Chemical Properties
form solid
color yellow to brownish-red to dark green
Sensitive air sensitive
Safety Information
MSDS Information
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Usage And Synthesis
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  1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters. 
  2. Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
  3. Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. 
Reactions of 1025477-38-6
Diacetato{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dtbm-segphos] Preparation Products And Raw materials
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