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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine

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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Suppliers list
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
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Products Intro: Product Name:5-(11bS)-5H-Dibenz[b,f]azepine-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl
CAS:942939-38-0
Purity:99% Package:1KG,5kg,10kg
Company Name: Aladdin Scientific
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Products Intro: Product Name:(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a'']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
CAS:942939-38-0
Purity:97%，99%ee Package:$70.9/100mg;$280.9/500mg;$504.9/1g;$2270.9/5g;Bulk package Remarks:97%，99%ee
Company Name: Energy Chemical  
Tel: 021-021-58432009 400-005-6266
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Products Intro: Product Name:5-(11bS)-Dinaphtho[2;1-d:1′;2′-f][1;3;2]dioxaphosphepin-4-yl-5H-dibenz[b;f]azepine
CAS:942939-38-0
Purity:97%;EE98% Package:100mg;1g;250mg;500MG Remarks:NULL
Company Name: Daicel Chiral Technologies (China)CO.,LTD  
Tel: 021-50460086-9 15921403865
Email: han_yajun@dctc.daicel.com
Products Intro: Product Name:5-(11bS)-5H-Dibenz[b,f]azepine-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl
CAS:942939-38-0
Purity:95%/98% Package:100MG;100G; 1KG Remarks:201063
Company Name: Tianjin Derchemist Science & Technology Co., Ltd.  
Tel: 22-58627059 13920586291
Email: zdcomcon@126.com
Products Intro: Product Name:(S)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
CAS:942939-38-0
Purity:98%,98%ee Package:25KG/10KG/5KG/1KG/500G/100G
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Basic information
Reaction
Product Name:5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
Synonyms:(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-dibenzo[b,f]azepine >=95% (elemental analysis);3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%;(S)-(+)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)-5H-DIBENZ[B,F]AZEPINE,MIN.97%;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%;(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine;5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
CAS:942939-38-0
MF:C34H22NO2P
MW:507.53
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:942939-38-0.mol
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Structure
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Chemical Properties
Melting point 246 °C
Boiling point 711.5±63.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka-2.70±0.20(Predicted)
form solid
color yellow
Sensitive air sensitive, moisture sensitive
Safety Information
WGK Germany 3
MSDS Information
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Usage And Synthesis
Reaction
  1. The ligand is used in the stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis.
  2. The ligand used in the direct, enantioselective iridium-catalyzed amination and (thio-) etherification of racemic allylic alcohols.
  3. The ligand used in an asymmetric, rhodium-catalyzed, intramolecular hydroacylation reaction. 
Reactions of 942939-38-0
UsesPhosphorous precursor for ligand synthesis
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Preparation Products And Raw materials
Tag:5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine(942939-38-0) Related Product Information