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Product Name:(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine, Walphos SL-W003-1 CAS:565184-29-4 Purity:97% Package:100mg;500mg;2g
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| (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Basic information |
Product Name: | (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine | Synonyms: | (1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene;(R)-1-[(R)-1-
(Dicyclohexylphosphino)ethyl]-
2-[2-
(diphenylphosphino)phenyl]ferro
cene;(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine, Walphos SL-W003-1;Ferrocene,1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]-, (1S)-;(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine;(R)-(-)-1-[(R)-2-(2''-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine | CAS: | 565184-29-4 | MF: | C42H48FeP210* | MW: | 670.623042 | EINECS: | | Product Categories: | | Mol File: | 565184-29-4.mol | |
| (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Chemical Properties |
Melting point | 87-96 °C | alpha | -8° ±2° (c 0.5, CHCl3) | form | Powder | color | orange |
| (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Usage And Synthesis |
Uses | (1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene is used in preparation of chiral Piperidines via asymmetric Hydrogenation of Dehydropiperidines using metal chiral Phosphine catalyst complexes. | Reactions | 1. Enantioselective synthesis of chiral fluoropiperidine via asymmetric hydrogenation of a vinyl fluoride.
2. Palladium/ClickFerrophos – Catalyzed asymmetric domino allylstannylation-Heck reaction of o-formylaryl
triflate.
3. Catalytic asymmetric alkylation of acylsilanes.
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| (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Preparation Products And Raw materials |
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