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| (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Basic information |
Product Name: | (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide | Synonyms: | tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;(tert-Butoxycarbonylmethyl)tripheenyphosphonium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98 %;triphenyl tert butoxycarbonyl Methyl phosphoniuM broMide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide | CAS: | 59159-39-6 | MF: | C24H26BrO2P | MW: | 457.34 | EINECS: | | Product Categories: | Olefination;Wittig Reagents;C-C Bond Formation | Mol File: | 59159-39-6.mol | ![(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Structure](CAS/GIF/59159-39-6.gif) |
| (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Chemical Properties |
Melting point | 178 °C (dec.)(lit.) | storage temp. | Inert atmosphere,Room Temperature | solubility | soluble in Methanol | form | powder to crystal | color | White to Almost white | BRN | 4631405 | CAS DataBase Reference | 59159-39-6(CAS DataBase Reference) |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26-37/39 | WGK Germany | 3 | HS Code | 29319019 |
| (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Usage And Synthesis |
Uses | Reactant for:
- Rhodium-catalyzed asymmetric hydrogenation reactions
- Wittig reaction
- Wittig methylenation
- Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
- Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
- Wittig chain extension reactions
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| (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Preparation Products And Raw materials |
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