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| | (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Basic information |
| Product Name: | (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide | | Synonyms: | tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;(tert-Butoxycarbonylmethyl)tripheenyphosphonium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98 %;triphenyl tert butoxycarbonyl Methyl phosphoniuM broMide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide | | CAS: | 59159-39-6 | | MF: | C24H26BrO2P | | MW: | 457.34 | | EINECS: | | | Product Categories: | Olefination;Wittig Reagents;C-C Bond Formation | | Mol File: | 59159-39-6.mol |  |
| | (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Chemical Properties |
| Melting point | 178 °C (dec.)(lit.) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | soluble in Methanol | | form | powder to crystal | | color | White to Almost white | | BRN | 4631405 | | CAS DataBase Reference | 59159-39-6(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | HS Code | 29319019 |
| | (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Usage And Synthesis |
| Uses | Reactant for:
- Rhodium-catalyzed asymmetric hydrogenation reactions
- Wittig reaction
- Wittig methylenation
- Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
- Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
- Wittig chain extension reactions
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| | (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Preparation Products And Raw materials |
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