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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-

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Products Intro: Product Name:Tris(trimethylsilyl)silanol
CAS:7428-60-6
Purity:>=95% Package:5G Remarks:902489-5G
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Products Intro: Product Name:2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
CAS:7428-60-6
Purity:96% HPLC Package:1g;10g;100g
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Products Intro: Product Name:Tris(trimethylsilyl)silanol >=95%
CAS:7428-60-6
Purity:>=95% Package:1ea;1g;5g Remarks:NULL
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Products Intro: CAS:7428-60-6
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Products Intro: CAS:7428-60-6
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Basic information
Product Name:2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
Synonyms:2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-;Tris(trimethylsilyl)silanol;Tris(trimethylsilyl)silanol >=95%;Hydroxy-tris(trimethylsilyl)silane
CAS:7428-60-6
MF:C9H28OSi4
MW:264.66
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Mol File:7428-60-6.mol
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Structure
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Chemical Properties
Boiling point 235.1±23.0 °C(Predicted)
density 0.833±0.06 g/cm3(Predicted)
pka15.57±0.53(Predicted)
Safety Information
MSDS Information
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Usage And Synthesis
UsesUnder a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Preparation Products And Raw materials
Raw materialsTrisilane, 2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)--->TETRAKIS(TRIMETHYLSILYL)SILANE-->TRIS(TRIMETHYLSILYL)SILANE-->2-Bromopropane
Preparation ProductsCHLOROTRIS(TRIMETHYLSILYL)SILANE-->Mesityl oxide
Tag:2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-(7428-60-6) Related Product Information