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(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol

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(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol Basic information
Product Name:(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol
Synonyms:(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol;Voaphylline hydroxyindolenine;Voaphylline hydroxyindolenine【neutral】;2H-3,13-Methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol, 13-ethyl-4,5,11,12,13,13a-hexahydro-, (1aR,5aR,13S,13aS)-
CAS:18269-16-4
MF:C19H24N2O2
MW:312.41
EINECS:
Product Categories:
Mol File:18269-16-4.mol
(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol Structure
(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol Chemical Properties
Boiling point 478.8±45.0 °C(Predicted)
density 1.38±0.1 g/cm3(Predicted)
pka12.38±0.40(Predicted)
Safety Information
MSDS Information
(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol Usage And Synthesis
DescriptionThis alkaloid from the leaf extract of Voacanga africana has the above structure in neutral or basic media as determined by spectral data, particularly the mass spectra. In acid solution it exists as the quaternary base. Reduction with KBH4 yields Voaphylline (q.v.) and conversely the base may be formed from the latter by oxidation with peracetic acid.
ReferencesKunesch, Das, Poisson., Bull. Soc. Chim. Fr., 3551 (1967)
(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol Preparation Products And Raw materials
Tag:(1aR,5aR,13S,13aS)-13-Ethyl-4,5,11,12,13,13a-hexahydro-2H-3,13-methanooxireno[9,10]azacycloundecino[5,4-b]indol-5a(1aH)-ol(18269-16-4) Related Product Information