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Hangzhou MolCore BioPharmatech Co.,Ltd. |
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Product Name:Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride CAS:944451-26-7 Purity:NLT 98% Remarks:MC581855
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Shaoxin Catsyn Co., Ltd. |
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+undefined-0575-82040869 +86-0575-82040869; |
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Product Name:Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((R)-H8-binap)]Cl CAS:944451-26-7 Purity:98% Min. Package:1G;1KG;100KG Remarks:SC10137
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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jkinfo@jkchemical.com |
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Product Name:Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl CAS:944451-26-7 Package:250mg;50mg
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Energy Chemical
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021-021-58432009 400-005-6266 |
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sales8178@energy-chemical.com |
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Product Name:(R)-RuCl[p-cyMene)(H8-BINAP)]Cl CAS:944451-26-7 Package:100MG,50MG
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Shanghai Incat Chemtech Co.,Ltd.
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021-57603038 13601791340 |
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307593986@qq.com |
Products Intro: |
Product Name:Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cyMene)rutheniuM(II) chloride, ?[RuCl(p-cyMene)((R)-H8-binap)]Cl CAS:944451-26-7 Purity:97% Remarks:公斤级;100G;50G;10G
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| Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Basic information | Reaction |
Product Name: | Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl | Synonyms: | Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl;[(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) dichloride;(R)-RuCl[p-cymene)(H8-BINAP)]Cl (R)-RuCl[p-cymene)(H8-BINAP)]Cl;Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)r;(R)-RuCL;[p-cymene)(H8-BINAP)]CL;RUCL(P-CYMENE)((R)-H8-BINAP)]CL;Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride | CAS: | 944451-26-7 | MF: | C54H52Cl2P2Ru | MW: | 934.93 | EINECS: | | Product Categories: | Ru | Mol File: | 944451-26-7.mol | ![Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Structure](CAS/20150408/GIF/944451-26-7.gif) |
| Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Chemical Properties |
Melting point | >100°C | storage temp. | 2-8°C | form | Powder | color | pale yellow | Sensitive | air sensitive |
| Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Usage And Synthesis |
Reaction |
- Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
- The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
| Uses | Takasago Ligands and Complexes for Asymmetric Reactions |
| Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Preparation Products And Raw materials |
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