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1-Naphthylamine NEW
Price | Get Latest Price |
Package | 25KG |
Min. Order: | 1KG |
Supply Ability: | 50000KG/month |
Update Time: | 2023-07-26 |
Product Details
Product Name: 1-Naphthylamine | CAS No.: 134-32-7 |
EC-No.: 205-138-7 | Min. Order: 1KG |
Purity: 99% | Supply Ability: 50000KG/month |
Release date: 2023/07/26 |
CAS: | 134-32-7 |
MF: | C10H9N |
MW: | 143.19 |
EINECS: | 205-138-7 |
Product Categories: | Building Blocks;C10;Amines;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Intermediates of Dyes and Pigments;Anilines, Aromatic Amines and Nitro Compounds;Chemistry;Aromatics;Intermediates;Fluorescent;134-32-7;bc0001 |
Mol File: | 134-32-7.mol |
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1-Naphthylamine Chemical Properties |
Melting point | 47-50 °C (lit.) |
Boiling point | 301 °C (lit.) |
density | 1.114 g/mL at 25 °C (lit.) |
vapor pressure | 0.003 hPa (20 °C) |
refractive index | 1.6703 |
Fp | >230 °F |
storage temp. | Store below +30°C. |
solubility | 1.7g/l |
form | flakes |
pka | 3.92(at 25℃) |
color | light tan to purple |
Odor | Ammonia odor |
PH | 7.1 (1g/l, H2O, 20℃) |
PH Range | Non& uorescence (3.4) to blue & uorescence (4.8) |
Water Solubility | Insoluble. 0.1698 g/100 mL |
Merck | 14,6398 |
BRN | 386133 |
Henry's Law Constant | 6.13 x 10-10 atm?m3/mol at 25 °C (thermodynamic method-GC/UV spectrophotometry, Altschuh et al., 1999) |
Exposure limits | TLV-TWA not assigned; carcinogenicity: Human Carcinogen (skin) (MSHA and OSHA). |
Major Application | color filter, photoresists, recording media, light-emitting device, disk, display device, oil products, construction materials, leather, textile, chalk, explosives |
CAS DataBase Reference | 134-32-7(CAS DataBase Reference) |
IARC | 3 (Vol. 4, Sup 7) 1987 |
NIST Chemistry Reference | 1-Naphthalenamine(134-32-7) |
EPA Substance Registry System | 1-Naphthalenamine (134-32-7) |
1-Naphthylamine Usage And Synthesis |
Chemical Properties | α-Naphthylamine exists as white needle-like crystals which turn red on exposure to air. Has a weak ammonia-like odor. Solubility in water is 0.16% at 20℃. It behaves as a typical primary aromatic amine in forming salts with strong acids (but not with acetic or benzoic acid) and readily forming N-acyl derivatives. 1-Naphthylamine couples with diazo compounds in the 4-position, with up to 10 % byproduct being formed by coupling in the 2-position. | |
Physical properties | White to yellow crystals or rhombic needles with an unpleasant odor. Becomes purplish-red on exposure to air. Odor threshold concentrations were 140–290 μg/m3 (quoted, Keith and Walters, 1992). | |
Uses | 1-Naphthylamine is used as a chemical intermediate in the synthesis of a wide variety of chemicals, the most important of which include dyes, tonic prints, Toning prints made with cerium salts, antioxidants, and herbicides. | |
Preparation | 1-Naphthylamine is prepared by reduction of 1-nitronaphthalene: Purified 1-nitronaphthalene was traditionally reduced with iron in boiling dilute hydrochloric acid, but modern plants use hydrogenation with a nickel catalyst. The 1-naphthylamine produced is further purified by distillation under vacuum. The content of 2-naphthylamine in the commercial product is specified at <10 ppm. | |
Application | 1-Naphthylamine is mainly used for the production of 1-naphthol. Other major uses are in the production of aminonaphthalenesulfonic acid dye intermediates and as a component of azo dyes. 1-Naphthylamine can also be used as a starting material to synthesize: [(S)-HY-Phos], a novel chiral phosphine-phosphoramidite ligand for use in rhodium-catalyzed asymmetric hydrogenation of various functionalized olefins. N-(naphthalen-1-yl)picolinamide. Pitnot-2, an inactive analog of clathrin inhibitor Pitstop 2. |
Quantity(Kilograms) | 1 - 10000 | >10000 |
Est. Time(days) | 5 | To be negotiated |
Company information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.
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